The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two molecules. The crystal packing features eight C—H⋯π interactions.
The crystal structure of the title salt, C13H19Cl2N2+·Cl−, has been reported previously [Homrighausen & Krause Bauer (2002).Acta Cryst.E58, o1395–o1396] based on room-temperature data, where it was found to contain a disordered chloropropyl group. We now present the structure at 100 K in which the chloropropyl group is ordered. The piperazine ring adopts a chair conformation with the exocyclic N—C bonds in equatorial orientations. The dihedral angle between the piperazine ring (all atoms) and the benzene ring is 28.47 (5)°. The chloropropyl group has an extended conformation [N—C—C—C = −177.25 (8) ° and C—C—C—Cl = 174.23 (7)°]. In the crystal, charge-assisted N—H...Cl hydrogen bonds link the cation and anion into ion pairs. Numerous weak C—H...Cl interactions link the ion pairs into a three-dimensional network. Short Cl...Cl contacts [3.2419 (4) Å] are also observed.
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