Polyvinyl chloride (PVC) is widely used as insulator in electrical engineering especially as cable insulation sheaths. In order to improve the dielectric properties, polymers are mixed with ceramics. In this paper, PVC composites with different weight percentages 2 wt.%, 5 wt.%, 8 wt.% and 10 wt.% were prepared and investigated. Loss index ([Formula: see text]) and dielectric constant ([Formula: see text]) have been measured using an impedance analyzer RLC. Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM) equipped with energy dispersive X-ray (EDX) have been used as characterization techniques. The incorporation of BaTiO3 does not modify the crystallinity and the morphology of the PVC but reduces the space charges, therefore the dielectric losses. The frequency response analysis has been followed in the frequency ranges (20–140 Hz and 115–1 MHz). Relaxation frequencies have been evaluated in each frequency range. Experimental measurements have been validated using Cole–Cole’s model. Experimental results show well that BaTiO3 as a filler improves the dielectric properties of PVC.

Cross-Linked Polyethylene (XLPE) is widely used as insulation in electrical engineering, especially as cable insulation sheaths. In order to improve the dielectric properties susceptible to be modified under the effects of thermal aging and water in an absorption environment, polymers are mixed with ceramics. In this paper, the influence of barium titanate (BaTiO3), on the dielectric properties of XLPE has been studied. Dielectric parameters have been measured using an impedance analyzer RLC (WAYNE KERR 6420 type). Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy and X-ray diffraction were used as characterization techniques. The study has been carried out on two samples of XLPE. A pure sample of each were studied as a unloaded samples to be compared with samples of 5%wt, 10%wt, 15%wt and 20%wt. BaTiO3 loaded XLPE. Afterwards, the composites were subject to humidity and to thermal aging. The incorporation of BaTiO3 1[Formula: see text]C does not modify the crystallinity and morphology of the XLPE and 2[Formula: see text]C reduces the space charges therefore the dielectric losses. [Formula: see text], [Formula: see text] and loss index are measured. Frequency response analysis has been followed in the frequency range (20–300 Hz). Experimental results show well that BaTiO3 as nano-filler improves the dielectric properties of XLPE but in excessive content can drive to the cracking and therefore to absorption of water.

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Poly-Vinyl Chloride (PVC) is a commonly used material used in cable insulation sheaths, but its dielectric properties can be negatively impacted by electric aging. This study investigates the use of nano-fillers, specifically alumina (Al2O3), titanium dioxide (TiO2), calcium carbonate (CaCO3), and barium titanate (BaTiO), in order to improve the dielectric properties of PVC. Films of PVC were doped with nano-fillers and were then exposed to an alternating voltage of 15kV for various time periods (1, 2, and 3 hours). The dielectric properties of PVC were measured using an impedance analyzer, and the results indicated that the use of these nano-fillers had a positive effect on the dielectric characteristics of PVC.