Cross sections for elastic scattering of low-energy electrons by tetrahydrofuran, a prototype for the furanose ring found in the backbone of DNA, have been measured and calculated over a wide energy range, with an emphasis on energies below 6 eV, where previous data are scarce. The measurements employ a thin-aperture version of the relative-flow method, while the calculations employ the Schwinger multichannel method with an extensive treatment of polarization effects. Comparisons with earlier results, both experimental and theoretical, are presented and discussed. A proper accounting for the strong permanent electric dipole of tetrahydrofuran is found to be essential to obtaining reliable cross sections, especially at energies below 5 eV.

We report measured and calculated cross sections for elastic scattering of low-energy electrons by isopropanol (propan-2-ol). The experimental data were obtained using the relative flow technique with helium as the standard gas and a thin aperture as the collimating target gas source, which permits use of this method without the restrictions imposed by the relative flow pressure conditions on helium and the unknown gas. The differential cross sections were measured at energies of 1.5, 2, 3, 5, 6, 8, 10, 15, 20, and 30 eV and for scattering angles from 10 • to 130 • . The cross sections were computed over the same energy range employing the Schwinger multichannel method in the static-exchange plus polarization approximation. Agreement between theory and experiment is very good. The present data are compared with previously calculated and measured results for n-propanol, the other isomer of C 3 H 7 OH. Although the integral and momentum transfer cross sections for the isomers are very similar, the differential cross sections show a strong isomeric effect: In contrast to the f -wave behavior seen in scattering by n-propanol, d-wave behavior is observed in the cross sections of isopropanol. These results corroborate our previous observations in electron collisions with isomers of C 4 H 9 OH.

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