The homoleptic triply-ligated cation in two silyl chloride salt solvates of 1-oxo-2-pyridinone is found to co-crystallize as a mixture of fac and mer isomers. A related silyl cation of 1-oxo-2-pyridinethione is found as the fac isomer.
Während N‐Methyl‐ und N‐Phenyl‐phthalamidin (Ia), (Ib) miLLithiumalanat zu den Isoindolen (IIa), (IIb) reduziert werden, wird aus dem Benzylderivat (Ic) mit Lithiumalanat (IIIc) und nur mit Natrium‐bis‐(2‐methoxyäthoxy)‐ aluminiumhydrid (IIc) erhalten.
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