The influence of non magnetic impurities in the 2d XY model is investigated through Monte Carlo (MC) simulations. The general picture of the transition is fully understood from the Harris criterion which predicts that the universality class is unchanged, and the Berezinskii-Kosterlitz-Thouless description of the topological transition remains valid. We nevertheless address here the question about the influence of dilution on the quasi-long-range order at low temperatures. In particular, we study the asymptotic of the pair correlation function and report the MC estimates for the critical exponent η at different dilutions. In the weak dilution region, our MC calculations are further supported by simple spin-wave-like calculations.

Systems with global symmetry group O(2) experience topological transition in the two-dimensional space. But there is controversy about such a transition for systems with global symmetry group O(3). As an example of the latter case, we study the Lebwohl-Lasher model for the two-dimensional liquid crystal, using three different methods independent of the proper values of possible critical exponents. Namely, we analyze the at-equilibrium order parameter distribution function with (1) the hyperscaling relation; (2) the first-scaling collapse for the probability distribution function; and (3) the Binder's cumulant. We give strong evidence for definite lack of a line of critical points at low temperatures in the Lebwohl-Lasher model, contrary to conclusions of a number of previous numerical studies.

Simulations of nematic-isotropic transition of liquid crystals in two dimensions are performed using an O2 vector model characterized by nonlinear nearest neighbor spin interaction governed by the fourth Legendre polynomial P4. The system is studied through standard finite-size scaling and conformal rescaling of density profiles of correlation functions. A topological transition between a paramagnetic phase at high temperature and a critical phase at low temperature is observed. The low temperature limit is discussed in the spin wave approximation and confirms the numerical results.

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The process of equilibration of the tetradecane-water interface in the presence of sodium hexadecane-benzene sulfonate is studied using intensive atomistic molecular dynamics simulations. Starting as an initial point with all of the surfactants at the interface, it is obtained that the equilibration time of the interface (several microseconds) is orders of magnitude higher than previously reported simulated times. There is strong evidence that this slow equilibration process is due to the aggregation of surfactants molecules on the interface. To determine this fact, temporal evolution of interfacial tension and interfacial formation energy are studied and their temporal variations are correlated with cluster formation. To study cluster evolution, the mean cluster size and the probability that a molecule of surfactant chosen at random is free are obtained as a function of time. Cluster size distribution is estimated, and it is observed that some of the molecules remain free, whereas the rest agglomerate. Additionally, the temporal evolution of the interfacial thickness and the structure of the surfactant molecules on the interface are studied. It is observed how this structure depends on whether the molecules agglomerate or not.