An approach to solve the limitations of autologous bone grafting procedures in bone injury treatment is to develop bioactive coatings in the implantation system. The objective of this work is to compare the temperature effect on the stability of hydroxyapatite, graphene, and collagen colloidal suspensions to be used as biocompatible and bioactive coatings on a carbon fiber composite surface. Synthesized hydroxyapatite was assessed by X-ray diffraction. Zeta potential at different temperatures was evaluated. Specimens were characterized using scanning electron microscopy and Raman analysis. The results showed that the best hydroxyapatite/graphene ratio was 85/15, while those of the hydroxyapatite/ collagen mixtures were 85/15. A hydroxyapatite/graphene/collagen mixture was synthesized based on these results.
In recent decades, there has been an increase in the research for the development and improvement of dye sensitized solar cells (DSSCs), owing to their singular advantages such as greater efficiency in energy conversion and overall performance in adverse environmental conditions. Therefore, work is carried out to enhance the energy efficiency of the components of the DSSCs: photoanode, counter-electrode, electrolyte, and dye sensitizer layer. Electrospun nanofibers in particular, have showed to be a novel alternative as components in DSSCs, mainly for energy conversion and as collector materials due in part to their tridimensional structure, high contact surface area and conductivity. Moreover, the incorporation of metallic compounds into nanofibers is advantageously employed in the electrospinning technique, owing to their conductivity and optical properties. Therefore, the present work consists of a detailed recompilation of the use of electrospun nanofibers loaded with metallic compounds and their application in DSSCs. The functionality of the components of DSSCs, parameters and experimental conditions of electrospinning, such as the intrinsic aspects in the polymer solution, are discussed and applied to the photoanode, counter-electrode and electrolyte of the DSSC. Lastly, the use of the electrospinning technique in combination with the use of metallic compounds could provide a great approach for the developing of DSSCs, with superior efficiency, high stability and durability.
Key indicatorsSingle-crystal X-ray study T = 294 K Mean (C-C) = 0.007 Å R factor = 0.050 wR factor = 0.130 Data-to-parameter ratio = 7.5For details of how these key indicators were automatically derived from the article, see
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