Electrospinning has been considered a straightforward way of producing nano and micro fibers. In this work we are analyzing variations of the conventional electrospinning process to better understand and explore the effect of electrostatic interactions. The variations we are investigating include the insertion of polymer inside the electric field keeping the capillary for polymer injection at a floating potential. In this way we are exploring different mechanisms of charge induction. Also, we are using different setup configurations including: same as electrospinning, parallel macro and micro electrodes. Image analysis reveals the occurrence of instabilities/oscillations of the polymer flow (caused by redistribution of charges) leading to the deposition of fibers and improving polymer flow directionality. Fiber orientation on the substrate can be obtained using parallel macro and micro electrodes.
It is well known that in printed circuits boards assembled by SMT technology may occur electrochemical migration (ECM). The electrochemical migration may become a potential reliability problem in electronic soldering when lead free technology is used in soldering electronic devices. Electrochemical migration is an electrochemical process where metal on an insulating material, in a humid environment and under an applied electric field, leaves its initial location in ionic form and redeposits. In a PCB two adjacents terminal may behave as electrodes so the dendrites grow from cathode to anode. A structure with a comb shape printed on FR4 substrate was used in the experiments. The distance between the fingers was 105 or 254 micron, in order to simulate a real distance between dispositive terminals. The parameters considered during the experiments were surface finishing, solder paste composition, distance between terminals and applied voltage. Al the experiments were performed two times. Tin was the main metal that migrates.
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