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Enhanced power conversion efficiency is reported in inverted polymer solar cells when an ultrathin layer of strontium fluoride (SrF 2 ) is evaporated on the surface of the solution-processed zinc oxide (ZnO) electron transport layer. The photoactive layer is made up of bulk heterojunction composites of poly [4,8-bis(5(2-ethylhexyl) and [6,6]-phenyl-C 71 -butyric acid methyl ester. The ZnO film acts as an effective electron transport layer, whereas the ultrathin SrF 2 layer improves the energy level alignment and enhances the built-in potential via the formation of an interfacial dipole layer at the interfaces between the ZnO film and the photoactive layer, resulting in an enhanced electron extraction efficiency and a decreased carrier recombination loss. Furthermore, the SrF 2 layer reduces the inherent incompatibility between the hydrophilic ZnO film and the hydrophobic photoactive layer. As a result, all the photovoltaic performance parameters are remarkably improved, leading to a high efficiency of up to 10.46% (with a fill factor of 71.38%), corresponding to a ca. 21% improvement over the reference device performance (8.64%). The use of a ZnO/SrF 2 stacked interlayer provides a simple, but effective, approach to obtain high-efficiency inverted PSCs.

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