The solubility of dilute SO 2 in aqueous HCl and NaCl solutions was determined at 298.15 K as a function of ionic strength up to 3 mol‚L -1 , in the partial pressure range between (0.075 and 1.8) kPa. Measurements were carried out by a saturation method using a laboratory batch reactor. Equations to correlate the apparent Henry's law constant, H m , and the apparent first dissociation constant, K m1 , were obtained as a function of ionic strength. Comparisons between experimental results and theoretical predictions were also made. A model based on the classical Sechenov equation was tested, and a new value for the SO 2 gas-specific parameter was obtained to calculate H m . Two different models were considered for calculating the activity coefficients to determine K m1 . An extended version of the Debye-Hu ¨ckel theory described the experimental results for ionic strengths below 0.1 mol‚L -1 . The Pitzer model was in good agreement with the experimental data in the ionic strength range between (0 and 3) mol‚L -1 . The close fit between measured and calculated data showed that the selected models can be successfully used for estimating the solubility of SO 2 in salt solutions at low partial pressures.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.