The increase in waste has motivated the adoption of the circular economy concept, which assumes particular relevance in the case of plastic materials. This has led to research of new possibilities for recycling plastics after their end-of-life. To achieve this goal, it is fundamental to understand how the materials’ properties change after recycling. This study aims to evaluate the thermal and mechanical properties of recycled plastics, namely polycarbonate (PC), polystyrene (PS), glass fibre-reinforced polyamide 6 (PA6-GF30), and polyethylene terephthalate (PET). With this purpose, injected samples were mechanically recycled twice and compared through thermal and mechanical tests, such as differential scanning calorimetry, hardness, tensile strength, and the melt flow rate. The results show that the amorphous materials used do not suffer significant changes in their properties but exhibit changes in their optical characteristics. The semicrystalline ones present some modifications. PET is the material that suffers the biggest changes, both in its flowability and mechanical properties. This work demonstrates that the mechanical recycling process may be an interesting possibility for recycling depending on the desired quality of final products, allowing for some materials to maintain comparable thermal and mechanical properties after going through the recycling process.

In this study, we describe the design and fabrication of an industrial injection moulding system that can be mounted and used on the NCD-SWEET small-angle X-ray scattering beamline at ALBA. We show how highly useful time-resolved data can be obtained using this system. We are able to evaluate the fraction of the material in the mould cavity and identify the first material to solidify and how this varies with the injection temperature. The design follows current industrial practice and provides opportunities to collect time-resolved data at several points within the mould cavity so that we can build up a 4D perspective of the morphology and its temporal development. The quantitative data obtained will prove invaluable for the optimisation of the next generation of injection moulding techniques. This preliminary work used results from the injection moulding of a general-purpose isotactic polypropylene.

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We describe the design and fabrication of an industrial injection moulding system which can be mounted and used on the NCD-SWEET Small-angle X-Ray Scattering Beamline at ALBA. We show how highly useful time-resolved data can be obtained using this system. We are able to evaluate the fraction of material in the mould cavity and identify the first material to solidify and how this varies with the injection tem-perature. The design follows current industrial practice and provides opportunities to collect time-resolved data at several points within the mould cavity so we can build up a 4D perspective of the morphology and its temporal development. The quantitative data obtained will prove invaluable for the optimisation of the next generation of in-jection moulding techniques. This preliminary work used results from the injection moulding of a general purpose isotactic polypropylene.