Synthesis of monodisperse iron-platinum (FePt) nanoparticles by reduction of platinum acetylacetonate and decomposition of iron pentacarbonyl in the presence of oleic acid and oleyl amine stabilizers is reported. The FePt particle composition is readily controlled, and the size is tunable from 3- to 10-nanometer diameter with a standard deviation of less than 5%. These nanoparticles self-assemble into three-dimensional superlattices. Thermal annealing converts the internal particle structure from a chemically disordered face-centered cubic phase to the chemically ordered face-centered tetragonal phase and transforms the nanoparticle superlattices into ferromagnetic nanocrystal assemblies. These assemblies are chemically and mechanically robust and can support high-density magnetization reversal transitions.

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In recent years, the stability of recorded data against thermal decay has become an important criterion for judging the performance of magnetic recording systems. Continued growth of storage densities in the presence of thermally activated behaviour, often called the `superparamagnetic effect', requires new innovations in the recording system in general, and the recording media, in particular. This paper reviews some of the recent advances in recording media (e.g. oriented and antiferromagnetically coupled media) that have helped magnetic recording to maintain the areal density growth rate. However, more innovations and novel architectures are needed for the solutions of tomorrow. Among the more promising media approaches, which are discussed in this paper, are perpendicular, patterned and self-assembled nanoparticle media. Additionally, thermally assisted recording is also reviewed as it combines good writeability with high thermal stability.