The commercial acrylic copolymer Paraloid B72 (PB72) and a synthesized nanostructured material (AMF) bearing silsesquioxane, methacrylate and fluorine units were analyzed to assess their performances as protective coatings for the conservation of Neolithic Cucuteni ceramic pottery when submitted to UV ageing. In the context of comparative evaluation of the protective efficiency, the present paper reports the use of a functional coating that operates via specific photochemical transformations at the coating-air interface as a UV resistant protection coating for cultural heritage artefacts. The main factors that influenced the photo-degradation behavior of the polymeric materials included their structure, the properties at the polymer/air interfaces, and the preferential orientation of functional groups at the surface of the polymeric coatings.
Chemical reactions with oscillating behavior can present a chaos state in specific conditions. In this study, we analyzed the dynamic of the chaotic Belousov–Zhabotinsky (BZ) reaction using the Györgyi–Field model in order to identify the conditions of the chaos behavior. We studied the behavior of the reaction under different parameters that included both a low and high flux of chemical species. We performed our analysis of the flow regime in the conditions of an open reaction system, as this provides information about the behavior of the reaction over time. The proposed method for determining the favorable conditions for obtaining the state of chaos is based on the time evolution of the intermediate species and phase portraits. The synchronization of two Györgyi–Field systems based on the adaptive feedback method of control is presented in this work. The transient time until synchronization depends on the initial conditions of the two systems and on the strength of the controllers. Among the areas of interest for possible applications of the control method described in this paper, we can include identification of the reaction parameters and the extension to the other chaotic systems.
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