The modern theory of lipid membrane structure incorporates the concept of lateral stress profile. The latter represents the forces that act on any solute inside the membrane. We used this concept to propose two lipid probes that introduce minimal distortions into the lipid bilayer packing: the surface pressure isotherms and volt-potentials of the pure and mixed (probe-containing) lipid monolayers are equal. The probes represent a FRET pair. They are applicable in lipid transfer and vesicle fusion experiments.
Studies on copper(II) tetrafluorenyl porphyrinate (CuTFP) and copper(II) tetraphenyl porphyrinate (CuTPP) have been focused on the charge carrier transport in their solid films and electroluminescence of their composites. In the dye layers deposited by resistive thermal evaporation, the mobilities of holes and electrons are on the order of 10 −5 and 10 −6 cm 2 V −1 s −1 for the charge transport under the influence of traps, and the charge mobility reaches the order of 10 −3 cm 2 V −1 s −1 at space-chargelimited current in the nontrapping mode. For the dye molecules, the correlation between the mobility of charge carriers and the distribution of the electron density on the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO), which serve as hopping sites for holes and electrons, respectively, is considered. Organic light-emitting diodes incorporating the dye molecules as emitting dopants demonstrate electroluminescence in the near-infrared (IR) range.
Three new benzothiadiazole (BTD)-containing luminophores with different configurations of aryl linkers have been prepared via Pd-catalyzed cross-coupling Suzuki and Buchwald–Hartwig reactions. Photophysical and electroluminescent properties of the compounds were investigated to estimate their potential for optoelectronic applications. All synthesized structures have sufficiently high quantum yields in film. The BTD with aryl bridged carbazole unit demonstrated the highest electrons and holes mobility in a series. OLED with light-emitting layer (EML) based on this compound exhibited the highest brightness, as well as current and luminous efficiency. The synthesized compounds are not only luminophores with a high photoluminescence quantum yield, but also active transport centers for charge carriers in EML of OLED devices.
Various isomers of azomethine derivatives of mesoporphyrin IX were first obtained in the form of palladium complexes by the interaction of the so-called "phosphorus complex", produced in situ in the Vilsmeier
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