A map shows intrinsic vulnerability to pollution of the Chrzanów karst-fissured aquifer (273 km 2 ) in the southern part of Poland. This aquifer is intensively drained by numerous intakes and Zn-Pb ore mines. A DRASTIC-type parametric system was applied for groundwater vulnerability evaluation. Vulnerability assessment is based on six factors (depth to groundwater table, lithology of the unsaturated zone, net recharge, hydraulic conductivity of the aquifer, groundwater flow velocity, aquifer thickness). For the final vulnerability map construction at the scale of 1:50,000, a combination of the aquifer simulation model (using MODFLOW) and a geographical information system was applied. Maps of the net recharge, hydraulic conductivity of the aquifer and groundwater flow velocity were derived by aquifer modelling. Based on the vulnerability index (21-182), six relative vulnerability classes were selected. Reliability of the map has been verified.

Triassic carbonate aquifers in the Upper Silesia region, affected by intense withdrawal, have been investigated by means of isotopic analyses of (14)C, δ(13)C, δ(2)H, δ(18)O and (3)H. The isotopic examinations were carried out in the 1970s and in the early 1980s, and it was the first application of tracers to estimate age and vulnerability for the contamination of groundwater in this region. Similar isotopic analyses were conducted in 2007 and 2008 with the same Triassic carbonate formation. The isotopic examinations were performed within the confined part of the carbonate formation, wherein aquifers are covered by semi-permeable deposits. The direct recharge of the aquifer occurs in the outcrop areas, but it mainly takes place due to percolation of the water through aquitards and erosional windows. The Triassic aquifer has been intensively drained by wells and by lead-zinc mines. Nowadays, the declining water demand and closure of some mines have induced a significant increase in the water table level. The detailed analysis of the results, including the radiocarbon age corrections and the comparison of radioisotope activities, has made it possible to estimate the range of residence time within the carbonate Triassic aquifer. This range from several tens to several tens of thousands indicates that the recharge of aquifers might have occurred between modern times and the Pleistocene. The apparent age of the water estimated on the basis of (14)C activity was corrected considering the carbon isotope exchange and the diffusion between mobile water in fractures and stagnant water in micropores. The obtained corrected period of recharge corresponds to the result of investigations of noble gases, which were carried out in the 1990s. In almost half of the cases, groundwater is a mixture of young and old water. The mixing processes occur mainly in areas of heavy exploitation of the aquifer.

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