We report a DFT and experimental study of the effects of the surface composition of a Ni/Ag alloy on methane activation and steam methane reforming compared to a pure Ni catalyst.

No abstract

Microbeads of metal ion-imprinted polymers (MIIPs) were prepared by a novel precipitation polymerization technique, in which copper methacrylate monomer and ethylene glycol dimethacrylate crosslinker were copolymerized in a rotary evaporator. The prepared microbeads had mono-or narrow size dispersity, and their sizes increased from 1 to 4 lm with decreasing solvent amount or increasing initiator concentration. The absorption capacity and selectivity of the imprinted polymer for copper ion were determined in the presence of various competitive metal ions. As results, adsorption equilibrium was quickly achieved in about 10 min with high absorbability (about 90%). The effects of pH, initial metallic ion concentration, and MIIP bead size on the absorption capacity were investigated. The Cu(II)-imprinted polymers exhibited extremely high selectivity, which was much higher than that of corresponding blank polymers.