In this study, TiO2 nanofibers were prepared with Polyvinylpyrrolidone (PVP) polymer using sol-gel method via electrospinning technique. Owing to the advantages of small fiber diameter, tunable porosity, low cost, large surface to volume ratio, structure control, light-weight, and less energy consumption, electrospun nanofibers are evolving as an adaptable material with a number of applications, in this case for filtration and environmental/virus protection. Different samples of TiO2/PVP nanofibers have been prepared by changing the parameters to achieve the best result. As the polymer concentration was increased from 6 to 8 wt.% of PVP, diameter of the resultant fibers was seen to be increased, implying decrease in the pore-size of the fibers up to 1.4 nm. Surface morphology has been checked via Scanning Electron Microscope (SEM) images. Crystalline nature has been analyzed by X-ray Crystallography. Using the Bruanauer-Emmett-Teller (BET) test, surface area and porosity has been checked for the suitable application. The synthesized TiO2/PVP nanofibers have tremendous practical potentials in filtration and environmental remediation applications.
In recent decades, the use of photocatalysts in the evolution of hydrogen (H2) has received much attention. However, the use of the well-known titanium oxide and another photocatalyst as a base for noble metals is limited due to their major weakness in electron-hole pair separation. The use of cocatalysts can be a good way to overcome this problem and provide better performance for the evolution of hydrogen. In this review, suitable high-efficiency cocatalysts for solar hydrogen production have been thoroughly reviewed. New strategies and solutions were examined in terms of increasing the recombination of charge carriers, designing reactive sites, and enhancing the wavelengths of light absorption. Several new types of cocatalysts based on semiconductors in noble groups and dual metals have been evaluated. It is expected that these photocatalysts will be able to reduce the activation energy of reaction and charge separation. In this regard, the existing views and challenges in the field of photocatalysts are presented. The characteristics of monoatomic photocatalysts are reviewed in this manuscript and the latest advances in this field are summarized. Further, the future trends and upcoming research are also briefly discussed. Finally, this review presents noble metal-based photocatalysts for providing suitable photocatalysts on a larger scale and improving their applicability.
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