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Ti-MWW, one of the latest titanium-silicalite catalysts, has been prepared by direct hydrothermal synthesis using hexamethyleneimine as a structure-directing agent. The characteristic of the catalyst was performed by means of the following methods: XRD, SEM, IR, UV-vis and X'Ray microanalysis. The catalytic properties of Ti-MWW have been compared with those of the conventional titanium-silicalites TS-1 and TS-2 in the epoxidation of allyl alcohol with hydrogen peroxide. The process has been described by the following main functions: the selectivity of the transformation to glycidol in relation to allyl alcohol consumed, the conversions of the substrates (allyl alcohol and hydrogen peroxide) and the selectivity of the transformation to organic compounds in relation to hydrogen peroxide consumed.

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The results of the epoxidation of allyl alcohol with 30% hydrogen peroxide over the Ti-MWW catalyst have been presented. The studies were carried out under atmospheric pressure and in the presence of methanol as a solvent. The influence of the following technological parameters on the course of epoxidation was examined: temperature (20-60°C), the molar ratio of AA/H 2 O 2 (1:1-5:1), methanol concentration (5-90 wt%), catalyst content (0-5.0 wt%), reaction time (5-300 min) and intensity of stirring (0-500 rpm).