The S(0) → S(1) fluorescence excitation spectrum of jet-cooled 1H2N with origin at 25484 cm(-1) has been measured. Twelve totally symmetric modes and five non-totally symmetric modes have been assigned in the excitation spectrum. Theoretical calculations at DFT B3LYP/6-31G** and CIS/6-31G** levels indicate that the 1H2N molecular geometry is more planar in the S(1) state than in the ground state. The geometry of the naphthalene ring changes upon excitation and promotes a number of totally symmetric ring stretching modes, in the excitation spectrum. As a result of the geometry change upon excitation a number of non-totally symmetric modes gain intensity. Based on a rotational envelope fitting procedure the average excited rotational state lifetime was estimated to be between 7 and 16 ps for 0 ≤E≤ hc × 800 cm(-1) (E is excess energy above the S(1) origin). The decay rate coefficients, k, of the rotational S(1) states, are not constant over this range of excess energies. By applying a Golden Rule model, it was determined that internal conversion to S(0) is unlikely to be the sole non-radiative process contributing to the decay of the excited states. It was concluded that excited state intramolecular proton transfer (ESIPT) plays a role in the observed behaviour of the rate co-efficient with excess energy. The observation of (i) a sharp increase in rate coefficient, k, above an excess energy of ∼550 cm(-1), and (ii) a significant number of high intensity fluorescence excitation spectrum features above an excess energy of ∼700 cm(-1), may indicate the presence of an energy barrier of ∼550 cm(-1), between the enol and keto geometries in the S(1) state. This result supports the conclusions of S. De, S. Ash, S. Dalai and A. Misra, J. Mol. Struc. Theochem, 2007, 807, 33-41, who estimated a barrier to ESIPT of ∼750 cm(-1). It was concluded that ESIPT occurs in 1H2N, across an energy barrier with a rate constant, k(pt)≤ 10(11) s(-1). Hence, at low excess energies (≤ 550 cm(-1)), the observed emission band originates predominantly from the keto tautomer. Above an excess energy of ∼1600 cm(-1), 1H2N decays predominantly via a non-radiative mechanism.

The S(1)← S(0) fluorescence excitation spectrum of jet-cooled 2-hydroxy-1-naphthaldehyde (2H1N) with origin at 26,668 cm(-1) has been measured. Nine totally symmetric modes and three non-totally symmetric modes have been assigned in the excitation spectrum. Ab initio calculations indicate that 2H1N undergoes a planarity change upon excitation, which may account for the unusual intensity of non totally symmetric vibrational modes in the excitation spectrum. A number of low intensity features were observed on the low energy side of the origin which have been assigned to the 2H1N dimer rather than different ground state confomers of 2H1N. The origin of the S(1)← S(0) electronic transition of the dimer lies at ~26,401 cm(-1); combinations of two low frequency intermolecular modes of the dimer (59 cm(-1) and 17 cm(-1)) were also observed. The occurrence of excited state intramolecular proton transfer (ESIPT) in 2H1N cannot be proven on the basis of this work. A comparison of the (photo)physical properties of 2H1N with 1-hydroxy-2-naphthaldehyde (1H2N) [A. McCarthy and A.A. Ruth, PCCP, 2011, 13, 7485-7499 (Part 1)], however, indicate the plausibility of an ESIPT process in 2H1N. The strength of the intramolecular hydrogen bond (IMHB) in 2H1N was computed as ~10.6 kcal/mol, a value comparable to the IMHB strength of 1H2N. The establishment of a lower limit on the state lifetimes of 2H1N, of ~1.8 ps, indicates that any proposed ESIPT reaction in 2H1N may not proceed barrierlessly. Above an excess energy of ~1000 cm(-1), the intensity of the fluorescence excitation spectrum reduces significantly, indicating the onset of a non-radiative decay mechanism.

Illumination for line-scan machine vision systems is required to produce a highly asymmetric elliptical beam pattern, to maximize system speed and accuracy. The use of LED emitters with symmetric Lambertian emission patterns is challenging in this context, requiring significant beam reshaping. A design for a collimated line-light, with long working distance, utilizing LEDs with symmetric Lambertian emission patterns, is presented. Using a combination of Fresnel lenses and total internal reflection (TIR) optics, an elliptical beam with a high degree of collimation is achieved. TIR elements are designed based on an adaptation of a freeform lens design method published by Chen et al. [Opt. Express 20, 10 (2012)]. Practical performance of the design is verified experimentally using a prototype unit. In addition, the design is compared, using ray tracing software, to line-lights constructed using commercially available symmetric and elliptical TIR lenses, and its superior performance is confirmed. The optical design described is fully manufacturable and suitable for both smalland large-scale production.

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A low-cost multispectral imager was built using a multiwavelength LED PCB (light-emitting diode printed circuit board), 3D printed housing, and a monochrome camera, and it was controlled via National Instruments LabVIEW software coupled with some simple electronics. Multivariate data analysis was performed using freely available software packages. The device is sufficiently simple in its construction and operation to be of use in many undergraduate courses concerned with topics such as spectroscopy, chemometrics, and colorimetry.