Formaldehyde (FA) is an extremely active compound that is widely used in numerous applications. Given that FA is a known carcinogen, it is essential to remove it from the environment. Titanium dioxide (TiO2), due to its special physicochemical properties, is a promising adsorbent for the removal of specific organic compounds from aqueous solutions. In this study, the interaction of TiO2 with FA in the presence and absence of quartz sand, the most common mineral on the Earth’s surface, was investigated under static and dynamic (batch) conditions, at 25 °C. The experimental data suggested that the sorption of FA onto TiO2 can be described adequately by a pseudo-second order kinetic model, indicating that the main sorption mechanism was chemisorption. It was observed that the combination of TiO2 and quartz sand could1 lead up to effective removal of FA from aqueous samples.

<p>This study investigates the transport of pesticide thiophanate methyl (TM) as well as the co-transport of TM and titanium dioxide (TiO<sub>2</sub>) nanoparticles in a water saturated column packed with quartz sand under various water conditions. Several ionic strengths (Is) (1, 10, 50 and 100 mM) and pH (3, 5, 7, 10) values were examined. The results from the transport experiments  were fitted and analyzed with the use of the ColloidFit software, while the results from cotransport experiments were fitted with a modified mathematical model of Katzourakis and Chrysikopoulos (2015). The results suggested that the lowest mass recovery rate was for the co-transport experiments with the addition of NaCl. It was shown that TM has a weak affinity for sand but a relatively strong affinity for TiO<sub>2</sub> at high Is and acidic pH. Furthermore, salinity was shown to have significant effects on TM removal.</p>

Human activities in modern life are contributing significantly to global environmental pollution. With the need for clean drinking water ever increasing, so does the need to find new water-cleaning technologies. The ability of nanoparticles (NPs) to remove persistent pollutants from aqueous solutions makes them very important for use in water treatment technology. Titanium dioxide (TiO2) is recognized as an NP with unique optical, thermal, electrical, and magnetic properties and is widely used as an adsorbent material. Due to the extensive use of pesticides, their removal from the aquatic environment has gained widespread attention from the scientific community. In the present work, the transport of pesticide thiophanate methyl (TM), as well as the cotransport of TM and TiO2 nanoparticles, in a water-saturated column packed with quartz sand under various water conditions were investigated. Several ionic strengths (1, 10, 50, and 100 mM) and pH values (3, 5, 7, and 10) were examined. The results from the transport experiments were fitted and analyzed with the use of the ColloidFit software, while the results from the cotransport experiments were fitted with a modified version of a recently developed mathematical cotransport model. The results of this study suggested that the lowest mass recovery rate was for the cotransport experiments with the addition of NaCl. Furthermore, it was shown that TM has a weak affinity for sand but a relatively strong affinity for TiO2 at high ionic strength and acidic pH, probably accounting for the reduced mass recovery of TM in cotransport experiments.