Abstact. The results of the study to establish the species composition of microorganisms settled on samples of polyether-acrylate composites after they are kept in sea water and in climatic conditions of the black sea coast are presented. The composition of the curing system in the composite and the conditions of holding the samples have a significant effect on the species composition of microorganisms.
The results of a study of the cyclic strength of polyester-racrylate composites are presented. The mechanical properties of the samples were determined on a Shimadzu Autograph AG-X Series universal testing machine. Test process management and pre-processing of data obtained on this machine are performed using the TRAPEZIUM X * 1 software. The measurements were carried out with a constant velocity of movement of the active capture of 3 mm / min. The compression force was directed along the long axis of the sample. The cyclic mechanical impact on the sample was carried out according to the following scheme: “loading to a certain maximum stress σmax in a given cycle → complete unloading at the same speed → five times repeating the cycle with a given load σmax → repeating the five times cycling procedure with a stepwise change in maximum load σmax until the sample is destroyed. It is shown that a characteristic feature of the load – strain curves during cycling is the presence of hysteresis, which is especially significant in the first cycle. The first compressive loading of the sample leads to significant changes in the structure of PEA. In the second and subsequent cycles, the difference between the loading and unloading curves of the sample is noticeably smaller and depends little on the cycle number. Then the state of the sample is stabilized, and subsequent cycling affects it much weaker. It is characteristic that the maximum difference between the losses in the first and subsequent cycles is observed at the minimum initial voltage. At maximum loads, the unloading curve is steeper than the loading curve, and at low loads, vice versa. Hysteresis losses increase with increasing maximum load in the cycle, which corresponds to an increase in the contribution of the plastic component to the total deformation of the sample. The E (σ) dependences obtained during loading in the first cycle practically coincide with the loss curves. In subsequent cycles, a slight quantitative change in these curves is observed without changing their general nature. The dependences obtained by unloading the samples are fundamentally different from the dependences obtained by loading. In this case, the discrepancy between the E (σ) curves during loading and unloading in the composite is slightly weaker than in pure PEA.
Transport facilities along with mechanical loads are exposed to various aggressive environments, including chemical and biological, as well as climatic factors. Materials in the process of operation in the air in open areas, as well as in some buildings and structures, along with physical and chemical influences are exposed to microbiological influences, mainly microscopic fungi, which can use their individual components as a source nutrition. One of the effective ways to protect and repair building structures from microbiological damage is the use of polymer compositions in the form of paints, mastics and other compositions. It is important to select biological compositions that are resistant to biological damage and are obtained using various formulations of the curing system of the polymer binder and the components of the polymer-mineral mixture. Also relevant is the use of materials with high climatic resistance. The article substantiates the relevance of using modern concrete with improved physicomechanical and operational properties based on polymer binders to increase the climatic resistance of the structures of transport structures. The results of climatic tests of polyester acrylate composites are presented. The compositions with the highest resistance to the effects of the conditions of the Black Sea coast have been identified. A correlation was found between the most stable composition and the smallest variety of microorganisms that populate the surface of the samples after testing. Processing and description of the results made it possible to identify the compositions of polyester acrylate composites that can be recommended for use. The use of polyester acrylate binder for the manufacture of composite materials for the repair and manufacture of structures of transport structures is proposed.
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