The dielectric behavior of rocks affected by the known phase transition of supercooled water is the main problem we analyzed. Three different granitic rocks were used to perform dielectric measurements in the frequency range from 100 Hz to 1 MHz and temperatures 100-350 K. Thin cylindrical samples were prepared, and circular electrodes were established using silver conductive paint. A clear change in the dielectric measurements appears at T ∼ 220 K for one of the samples. This coincides with the known phase transition of supercooled water. Tightly bounded water confined in the pores of the rock do not crystallize at 273 K, but form a metastable liquid down to 200-220 K maintaining water polarization. Below this temperature, water molecules solidify and polarizability decreases. The rock presenting the most sizable change has a very low specific surface area of ∼0.09 m 2 g −1 , has connected porosity of ∼1.10%, and has the smallest degree of alteration. In addition, geochemical analyzes reveal a low percentage of hydration water in its structure confirming the role of pore water in this change. A comparison between water-saturated, oven-dried, and vacuum-dried samples was done. Finally, a logarithmic dependency of the critical temperature for the supercooled water phase transition with the measuring frequency was found.

After many years of war, great efforts have been made for the socio-economic development of Angola, particularly in the construction industry. Among the construction techniques, adobe is one of the most used in the province of Huambo, especially by low-income families, which constitute the majority. This technique was established as an intangible heritage in the culture of that population. Huambo province is located in the central region of Angola (Central Plateau). Adobe blocks are building elements with potential degradation by the action of water. Due to the subtropical climate, hot and humid, and geomorphology of the province, located at about 1000-2000 m of altitude and with an extensive river system, these buildings can be vulnerable and may present premature degradation, exacerbated by the lack of knowledge concerning the properties of the geomaterials used and techniques/solutions that allow their stabilization and conservation. This paper aims to present the main results of the study to investigate the influence on adobe performance in regard to the mineralogy and geochemistry of soils used in the production of adobes used in the construction of dwellings. The knowledge gained with this research can support the development of solutions for the common anomalies and problems in this construction, as well as to improve the strength and durability of the adobe units. For this purpose, soil samples were collected and mineralogical, geochemical, and physical tests were performed. Durability and erodibility tests were also performed on selected adobes, following the Geelong method. The results obtained with this research may contribute to the development of the knowledge concerning this sustainable building solution, which has a strong presence in the province of Huambo and neighbouring regions.

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