Visible light responsive, ferromagnetic, reusable Bi doped TiO2–ZrO2 nanocomposites exhibit enhanced photodegradation and mineralization of malachite green dye. Hydroxyl radicals, holes and superoxides are active species in photodegradation.
In
the quest for developing novel narrow band gap semiconductor
materials, the research in metal chalcogenides has gained a strong
attraction. In the present investigation, a surfactant-free hydrothermal
route has been followed to design hierarchical self-assembled flower-like
ZnIn
2
S
4
structures through control over precursor
concentration and hydrothermal processing parameters. Uniform hexagonal
marigold flower-like ZnIn
2
S
4
architectures (∼4
μm) were formed with self-assembly of petals (thickness ∼8–12
nm) forming rose-like structures and finally forming marigold flowers
in 24 h duration. The hierarchical ZnIn
2
S
4
flower
structure has been used as photocatalysts for the degradation of dye
and chlorinated phenols. Photodegradation demonstrates that the high
surface area from the porous flower architecture (∼72 m
2
/g) with an enhanced visible light absorption giving low band
gap energy (2.15 eV) is responsible for higher photocatalytic performance.
Complete degradation of the organic pollutants has been observed within
90 min in the presence of natural sunlight. To understand the participating
reactive species contributing to degradation, scavenger studies were
performed for deducing the plausible photocatalytic degradation pathways.
This study might open new insights into the design of novel hierarchical
structures.
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