Abstract. Since the development of the Ti54M titanium alloy in 2003, its application within the aerospace sector has gradually increased due to the combination of properties such as improved forgeability and machinability, low flow stress at elevated temperatures, and superplastic characteristics. However, for the successful exploitation of Ti54M a comprehensive understanding of its mechanical characteristics, microstructure stability, and superplastic behaviour is required.The superplastic forming of titanium alloys is characterised by high deformation at slow strain rates and high temperatures which influence the material microstructure, and in turn, determine the forming parameters. These mechanisms make the prediction of the material behaviour very challenging, limiting its application within the aerospace industry. Even though Ti54M has been commercially available for over 10 years, further studies of its mechanical and superplastic properties are still required with the aim of assessing its applicability within the aerospace industry as a replacement for other commercial titanium alloys. Therefore, in this work a study of the mechanical and superplastic properties of Ti54M, in comparison with other commercial titanium alloys used in the aerospace industry -i.e. Ti-6AL-4V, and Ti-6-2-4-2 -is presented. The final objective of this study, carried out at the Advanced Forming Research Centre (AFRC, University of Strathclyde, UK), is to obtain material data to calibrate and validate a model capable of estimating the behaviour and grain size evolution of titanium alloys at superplastic conditions.

Electrochemical machining (ECM) is a non-conventional machining process which is based on the localised anodic dissolution of any conductive material. One of the main applications of ECM is the polishing of materials with enhanced characteristics, such as high strength, heat-resistance or corrosion-resistance, i.e. electrochemical polishing. The present work presents an evaluation of the parameters involved in the ECM of Stainless Steel 316 (SS316) with the objective of predicting the resulting surface finish on the sample. The interest of studying ECM on SS316 resides on the fact that a repeatable surface finish is not easily achieved. ECM experimental tests on SS316 pipes of 1.5" (0.0381 m) diameter were conducted by varying machining parameters such as voltage, interelectrode gap, electrolyte inlet temperature, and electrolyte flow rate. The surface finish of the samples was then evaluated in order to find the significance of each of these parameters on the surface quality of the end product. Results showed that overvoltage, which is dependent on the interelectrode gap and the electrolyte temperature, is one of the main parameters affecting the surface finish; additionally there is a strong relationship between the resulting surface finish and the electrolyte flow. The interelectrode gap and inlet electrolyte temperature also affect the resulting surface finish but their influence was not so evident in this work. Finally, the variation of the electrolyte temperature during the process was found to have a great impact on the uniformity of the surface finish along the sample. We believe that this contribution enables the tailoring of the surface finish to specific applications while reducing manufacturing costs and duration of the ECM process

In electrochemical machining (ECM)-a method that uses anodic dissolution to remove metal-it is extremely difficult to predict material removal and resulting surface finish due to the complex interaction between the numerous parameters available in the machining conditions. In this paper, it is argued that a 3D coupled multiphysics finite element model is a suitable way to further develop the ability to model the ECM process. This builds on the work of previous researchers and further claims that the overpotential available at the surface of the workpiece is a crucial factor in ensuring satisfactory results. As a validation example, a real-world problem for polishing via ECM of SS316 pipes is modelled and compared to empirical tests. Various physical and chemical effects, including those due to electrodynamics, fluid dynamic, and thermal and electrochemical phenomena, were incorporated in the 3D geometric model of the proposed tool, workpiece, and electrolyte. Predictions were made for current density, conductivity, fluid velocity, temperature, and crucially, with estimates of the deviations in overpotential. Results revealed a good agreement between simulation and experiment and these were sufficient not only to solve the immediate real problem presented but also to ensure that future additions to the technique could in the longer term lead to a better means of understanding a most useful manufacturing process.

Even though TIMETAL-54M (Ti-5Al-4V-0.6Mo-0.4Fe or Ti54M) has been commercially available for over 10 years, further study of its superplastic properties is still required in order to assess its applicability within the aerospace industry as a potential replacement for other commercial titanium alloys such as Ti-6Al-4V (Ti64). Ti54M is expected to obtain superplastic characteristics at a lower temperature than Ti64 due to its lower beta-transus temperature. The superplastic forming (SPF) capability of alloys that can be formed at lower temperatures has always attracted the interest of industry as it reduces the grain growth and alpha-case formation, leading to longer life for costly high temperature resistant forming tools. In this work, the SPF characteristics of both Ti54M and Ti64 have been examined by conducting tensile tests according to the ASTM E2448 standard within a range of temperatures and strain values at a fixed strain rate of 1 × 10-4/S. A high strain rate sensitivity and uniform deformation at high strains are key indicators in selecting the optimum superplastic temperature. This was observed at 815˚C and 925˚C for Ti54M and Ti64 respectively. The tensile samples were water quenched to freeze their respective microstructure evolution following superplastic deformation and SEM images were captured for grain size and volume fraction of alpha-phase analyses. A slightly higher alpha-grain growth rate was observed during superplastic deformation of Ti64. The initial fine-grain microstructure of Ti54M (~1.6 micron) resulted in a final microstructure with an average grain size of ~3.4 micron and optimum the alpha/beta ratio. Both the fine-grained microstructure and increased amount of beta-volume fraction promotes the superplastic behaviour of Ti54M by grain boundary sliding (GBS). Thus superplastic properties were observed for Ti54M at a lower temperature (~100˚C) than for Ti64.

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