Ni@diaza crown ether complex supported on magnetic nanoparticle was provided by grafting technique. The catalytic activity of Fe3O4@diaza crown ether@Ni was explored through one‐pot synthesis of 2,3‐dihydroquinazolin‐4(1H)‐ones and it was used as an efficient and recoverably constant nanocatalyst. FT‐IR, SEM, TEM, XRD, BET, ICP, EDS, and TGA techniques were employed to specify the nanocatalyst. This heterogeneous catalyst demonstrated acceptable recyclability and could be used again several times with no considerable loss of its catalytic activity.

In the present study, the Fe3O4@Glycerol-Cu complex supported magnetically as a nanoparticle was prepared by grafting. Firstly, Fe3O4 NPs were synthesized by FeCl3.6H2O and FeCl2.4H2O according to the reported method, and subsequently, the prepared MNP with 3-chloropropyltrimethoxysilane. After that, the support-glycerol was functionalized on the surface of MNP-(CH2)3Cl for graft and stabilization of copper metal. Our purpose is to use the Fe3O4@Glycerol-Cu as a green, recoverable, novel, and affordable nanocatalyst in the effective synthesis of 2-amino-4H-chromenes. FT-IR, XRD, TGA, BET, VSM, TEM, and SEM–EDX techniques were examined to characterize this nanocatalyst. This result demonstrates that copper and organic compounds have appropriately reacted, with the support of MNP-(CH2)3Cl, and the crystalline structure have preserved in the MNP-(CH2)3Cl/Glycerol-Cu nanocatalyst confirmed the formation of the base Cu complex grafted on the surface of the nanoparticles. Finally, as can be seen, the nanoparticle size is 5–15 nm. This heterogeneous nanocatalyst illustrated excellent recyclable behavior, and can be used several times without notable reduction of its activity.

Ni-PEG (polyethylene glycol) complex supported on magnetic nanoparticle was created by grafting. The catalytic activity of Fe 3 O 4 @PEG-Ni was explored through one-pot green synthesis of 2,3-dihydroquinazolin-4(1H)-ones and used as an efficient and recoverable nanocatalyst. FT-IR, XRD, EDS, BET, TGA, VSM and SEM techniques were employed to specify the nanocatalyst. This heterogeneous nanocatalyst demonstrated acceptable recyclability and could be reused several times with no considerable loss of its catalytic activity.