a b s t r a c tAsphaltene precipitation and subsequent deposition is a potential flow assurance problem for the oil industry nowadays. Moreover, because oil production is moving to more difficult production environments -e.g. deeper waters -or is focusing on extracting residual oil using enhanced oil recovery techniques, the significant changes of pressure, temperature and/or composition can aggravate the asphaltene deposition problems. One of the most common strategies to prevent or at least reduce asphaltene deposition is the utilization of chemical additives. However, there are still several unresolved challenges associated to the utilization of these chemicals: First, the experimental conditions and results obtained in the lab are not always consistent with the field observations. Also, in some cases these chemical additives seem to worsen the deposition problem in the field. Therefore, there is a clear need to revisit the commercial techniques that are used to test the performance of asphaltene inhibitors and to provide a better interpretation of the results obtained. In this work, a technique based on NIR spectroscopy is presented to evaluate the performance of three commercial asphaltene dispersants. The method presented in this work is faster and more reproducible compared to the available methods such as the Asphaltene Dispersion Test (ADT) and the Solid Detection System (SDS). Also, unlike the ADT test, our proposed method can evaluate the performance of the dispersants in a wide range of temperatures and compositions. The experimental evidence shows that the asphaltene dispersants neither shift the actual onset of asphaltene precipitation nor reduce the amount of asphaltene precipitated. We believe that some results that have been reported that suggest that asphaltene dispersants can actually shift the onset of asphaltene precipitation are an unfortunate combination of insufficient sensitivity of the commercial instruments used and the slowing down of the asphaltene aggregation process by the effect of the added dispersants. The chemical additive dosage, aging time and temperature effect on the asphaltene aggregation process are also discussed in this manuscript.With this work we aim to contribute to a better understanding of the variables that affect the performance of asphaltene dispersants, and the effect that these chemicals have on the complex multi-step mechanism of asphaltene precipitation and aggregation.

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Asphaltene deposition is a flow assurance problem that threatens the continuous production of crude oil. This problem is likely to get worse because of the current tendency to produce from deeper waters and also due to the implementation of enhanced oil recovery operations based on miscible injection of CO2 or hydrocarbon gas. In this article we present a review of the asphaltene precipitation and deposition problem in oil production, and we describe the commercial techniques used for its determination and quantification as well as their limitations. We also discuss the important progress achieved concerning modeling tools with enhanced capabilities that have been developed to forecast the occurrence and the magnitude of this problem. Prompt recognition of potential asphaltene deposition issues, either for new fields or as part of enhanced oil recovery projects, is necessary to implement successful prevention or mitigation strategies. Unfortunately, current commercial inhibitors have mixed results in the field and in some cases are responsible for worsening the deposition problem. After a thorough investigation we have elucidated a multi-step mechanism of asphaltene precipitation, aggregation and aging, which explains the poor performance of some chemicals and the limited capabilities of the current testing protocols. We provide some ideas for a new generation of asphaltene inhibitors and, for the cases in which asphaltene deposition has already occurred, we also provide a list of common techniques and best practices used for its remediation. With this work we aim to provide the reader with a broad understanding of this complex problem and to offer a starting point for the development of cost/effective strategies to manage asphaltene deposition in increasingly complex environments.