We report a facile method for the
synthesis of zinc oxide nanoparticles
(nZnOs) by rapidly heating a paste of zinc nitrate and sucrose on
the hot plate at 500 °C. The transmission electron microscopy
images revealed the spherical shape of the nZnO with an average size
of 35 nm. The band gap and the specific surface area of the nZnO were
measured to be about 3.32 eV and 80.11 m
2
/g, respectively.
The nZnO was utilized for the photocatalytic degradation of methyl
orange (MO) and methylene blue (MB) in water under the ultraviolet
(UV-B) light and sunlight irradiation. Photocatalysis was performed
in two types of water matrices, viz., the deionized water and the
simulated fresh drinking water. Almost a complete degradation of MO
and MB was obtained within 30 min of UV-B light irradiation. Under
sunlight irradiation, more than 95% of the MO solution underwent degradation
within 30 min. The photocatalytic stability of the nZnO was examined
for five cycles, and a similar activity was found throughout the cycles.
The photocatalytic generation of the hydroxyl radical (
•
OH) was confirmed by the terephthalic acid photoluminescence tests.
Moreover, the synthesis methodology was validated by triplicating
the nZnO synthesis. Every time, the nZnO demonstrated a similar photocatalytic
activity, which confirmed the robustness of the synthesis procedure.
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