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Expansive soils are conventionally treated with chemical stabilizers manufactured by energy-intensive processes that significantly contribute to carbon dioxide emissions globally. Geopolymers, which are synthesized from industrial byproducts rich in aluminosilicates, are a viable alternative to conventional treatments, as they are eco-friendly and sustainable. In this study, a metakaolin-based geopolymer was synthesized, and its effects on the strength and volume-change behavior of two native expansive soils from Texas, with a plasticity index over 20 were investigated. This paper elaborates on the geopolymerization process, synthesis of the metakaolin-based geopolymer, specimen preparation, and geopolymer treatment of soils. Comprehensive material testing revealed two clays with a plasticity index over 20. They were each treated with three dosages of the metakaolin-based geopolymer and cured in 100% relative humidity for three different curing periods. The efficiency of geopolymer treatment was determined by testing the control and geopolymer-treated soils for unconfined compressive strength (UCS), one-dimensional swell, and linear shrinkage. Field emission scanning electron microscope (FESEM) imaging was performed on the synthesized geopolymer, as well as on the control and geopolymer-treated soils, to detect microstructural changes caused by geopolymerization. A significant increase in UCS and reduction in swelling and shrinkage were observed for both geopolymer-treated soils, within a curing period of only 7 days. The FESEM imaging provided new insights on the structure of geopolymers and evidence of geopolymer formation in treated soils. In conclusion, the metakaolin-based geopolymer has strong potential as a lower-carbon-footprint alternative to conventional stabilizers for expansive soils.

Calcium-based stabilizers such as lime and cement control swell and shrinkage behavior and enhance strength properties for expansive soils through the formation of pozzolanic components. However, sulfate-bearing subgrade soils stabilized with calcium-based stabilizers might cause excessive swelling and shrinkage due to the formation of highly expansive minerals like ettringite and thaumasite. In this paper, one liquid ionic soil stabilizer (LISS) was evaluated as an alternative stabilizer used to control swelling and shrinkage behavior of expansive soils. A comprehensive laboratory experiment program including a linear shrinkage test, a one-dimensional swell test, and an unconfined compressive strength test, was designed and carried out on soils from Dallas, Texas before and after treatment. Three dosage levels of stabilizer and four different curing periods were investigated. Test results indicate that LISS is an effective stabilizing agent, which not only reduces swelling and soil plasticity but also increases soil strength. Furthermore, a similar type of LISS is utilized to treat the soil in Dallas via deep injection using a hydraulic pump. Field emission scanning electron microscopy results on the test soil showed that the stabilizing program is likely to work through clay flocculation and morphological variations in the clay particles.

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