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Ionically cross-linked polyelectrolyte complexes (PECs) of anionic poly(sodium 4-styrene sulfonate) (PSS) and cationic poly(diallyldimethylammonium chloride) (PDADMAC), xPSS.(1-x)PDADMAC, with molar fractions x ranging from 0.30 to 0.70, were prepared and subsequently dried. The PEC samples were analyzed by differential scanning calorimetry, and the ionic conductivity sigmadc of the samples was measured as a function of temperature by means of impedance spectroscopy. The thermograms display an endothermic peak in the temperature range of 90-143 degrees C, which is attributed to a glass transition of the PEC. The glass transition temperature Tg has a symmetric x dependence with a minimum at x=0.50. The temperature dependence of sigmadcT is not affected by the glass transition. The ionic conductivity of the samples before drying is three orders of magnitude larger than sigmadc after drying; nevertheless, their activation enthalpies are identical. Arrhenius parameters obtained from the systematic study of several PEC compositions are discussed. The ionic conductivity of the PSS-rich samples is significantly higher than sigmadc of PDADMAC-rich samples. This implies a relatively high Na+ mobility as compared to Cl(-) mobility in PEC. In contrast to the symmetric x dependence of Tg, the conductivity of PEC increases and the activation enthalpy decreases with increasing x in the investigated composition range. A strong x dependence of sigmadc is observed for PSS-rich PEC, which is attributed to a significant variation in the mobility of the charge carriers.

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