The article describes the results of finite-difference time-domain (FDTD) mathematical modeling of electric field strength distribution near the gold laser-induced periodic surface structures (LIPSS). Both theoretical and experimental results have been described for two fabricated morphologies: round «hill-like» and grating structures. The structures were fabricated by using a femtosecond Yb-fiber laser with a wavelength of λ=1032 nm, pulse duration τ=280 fs, and repetition rate υ=25 kHz. Morphological properties of the surfaces have been investigated by means of scanning electron microscopy (SEM). The plasmonic activity was analyzed by means of the surface-enhanced Raman spectroscopy (SERS) technique. FDTD-calculated electric field values were converted into the electromagnetic field enhancement coefficient and the theoretical SERS intensity. The prospects of the theoretical approach for LIPSS to evaluate optimal field amplification and light scattering parameters has been shown. The presented approach could be applied as a basis for performing the methods of controlled synthesis for LIPPS.
This paper describes a detailed study of the spectral homogeneity of human platelets using Surface-enhanced Raman spectroscopy (SERS). We used a combined approach based on multivariate methods as principal component analysis and pair correlation algorithms to investigate platelets spectral properties. The correlation coefficients for each sample have been calculated, and the average coefficient of determination has been estimated. The high degree of spectral homogeneity inside one probe and between them has been revealed. The prospects of obtained results usage for pathologies based on platelet conformations during cardiovascular diseases have been demonstrated.
This paper presents the reflection spectra of s - and p-polarized light and the refractive index spectra of anodized titanium surfaces modified by laser-induced periodic structures with gold nanoparticles. It is shown that these surfaces generate surface plasmons in the visible region of the spectrum, which leads to the formation of a negative values region in the refractive index.
In this paper, the plasmon resonance on electrochemically modified titanium surfaces synthesized by anodic dissolution method has been studied in the presence with gold ablative nanoparticles. The permittivity functions and reflection coefficients of p- and s-polarized light spectra on the titanium oxide surface of various modification (roughness) have been analyzed. Spectral features of the negative refractive index in the area of surface plasmon generation on the rough titanium-oxide film interface have been also presented in this paper.
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