Fused deposition modeling (FDM) is an additive manufacturing (AM) process that is often used to fabricate geometrically complex shaped prototypes and parts. It is gaining popularity as it reduces cycle time for product development without the need for expensive tools. However, the commercialization of FDM technology in various industrial applications is currently limited due to several shortcomings, such as insufficient mechanical properties, poor surface quality, and low dimensional accuracy. The qualities of FDM-produced products are affected by various process parameters, for example, layer thickness, build orientation, raster width, or print speed. The setting of process parameters and their range depends on the section of FDM machines. Filament materials, nozzle dimensions, and the type of machine determine the range of various parameters. The optimum setting of parameters is deemed to improve the qualities of three-dimensional (3D) printed parts and may reduce post-production work. This paper intensively reviews state-of-the-art literature on the influence of parameters on part qualities and the existing work on process parameter optimization. Additionally, the shortcomings of existing works are identified, challenges and opportunities to work in this field are evaluated, and directions for future research in this field are suggested.

Fused filament fabrication (FFF) is one of the most popular additive manufacturing (AM) processes that utilize thermoplastic polymers to produce three-dimensional (3D) geometry products. The FFF filament materials have a significant role in determining the properties of the final part produced, such as mechanical properties, thermal conductivity, and electrical conductivity. This article intensively reviews the state-of-the-art materials for FFF filaments. To date, there are many different types of FFF filament materials that have been developed. The filament materials range from pure thermoplastics to composites, bioplastics, and composites of bioplastics. Different types of reinforcements such as particles, fibers, and nanoparticles are incorporated into the composite filaments to improve the FFF build part properties. The performance, limitations, and opportunities of a specific type of FFF filament will be discussed. Additionally, the challenges and requirements for filament production from different materials will be evaluated. In addition, to provide a concise review of fundamental knowledge about the FFF filament, this article will also highlight potential research directions to stimulate future filament development. Finally, the importance and scopes of using bioplastics and their composites for developing eco-friendly filaments will be introduced.

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A solvent free solid composite polymer electrolyte (SCPE) film consisting of high molecular mass polyethylene oxide (PEO) with sodium perchlorate (NaClO 4 ) as electrolytic salt and cubic zirconium oxide (ZrO 2 ) nanoparticles as the filler has been prepared by solution casting technique to influence the transport properties. X-ray diffraction and Fourier transform infrared spectroscopy confirm the formation of the SCPE film, whereas atomic force microscopy reveals the presence of a network of interconnected nanoparticles forming uniform surface feature of relatively low roughness. The highest ionic conductivity (r ¼ 6.96 Â 10 À5 S-cm À1 ) for PEO 25 -NaClO 4 with 5 wt. % ZrO 2 nanoparticles of the smallest size 4.5 nm is an order of magnitude higher than the pure PEO 25 -NaClO 4 at room temperature. The conductivity enhancement is due to the creation of additional sites and favorable conduction pathways for ionic transport through Lewis acid-base type interactions between the polar surface groups of the ceramic filler and the electrolyte ionic species.

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