Recently, the anisotropic single crystalline SnSe has gained tremendous interest as a promising thermoelectric material. The elastic constants of such anisotropic crystals are notoriously difficult to measure yet play a crucial role in many thermodynamic properties. We report for the first time the nine independent elastic constants of its stiffness tensor as measured by resonant ultrasound spectroscopy. Our experimental values of the elastic constants are in good agreement with those reported by the density functional theory of SnSe, except for C 12 . The Voigt−Reuss− Hill method was used to determine the isotropic polycrystalline elastic moduli from the measured elastic constants of SnSe, which were found to be in agreement with theoretical values. Notably, the heat capacity of single crystalline SnSe deduced from our measured elastic moduli is in excellent agreement with the room temperature value of heat capacity determined from thermal transport measurements.
The primary goal of this study was to characterize the influence of the pore‐saturated gas media and their physical properties on the elasticity of porous ceramic materials. Resonant ultrasound spectroscopic measurements were performed on test specimens of alumina with ~40% porosity, zirconia with ~48% porosity, and sintered fully dense zirconia to determine the hydrostatic pressure‐dependent macroscopic elasticity. Here, we report the variation of elasticity of porous and full dense samples over approximately five orders of magnitude (800‐0.02 psi) in absolute pressure. The time evolution of mechanical equilibrium of the porous materials at low pressure and high‐temperature conditions will also be discussed.
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