The use of argan nut shell as a precursor for producing activated carbon was investigated in this work. Two activated carbons AC-HP and AC-Na were prepared from argan nut shell by chemical activation method using phosphoric acid (HPO) and sodium hydroxide (NaOH), respectively. Textural, morphological, and surface chemistry characteristics were studied by nitrogen physisorption, TGA, SEM, TXRF, FTIR, XRD, and by determining the pH of the AC-HP. The adsorption experiments revealed that AC-HP was more efficient in adsorption of BPA due to high specific surface area (1372 m/g) compared to AC-Na (798 m/g). The obtained adsorption data of BPA on AC-HP correlated well with the pseudo-second-order model and the Langmuir isotherm (Qmax = 1250 mg/g at 293 K). The thermodynamic parameters (ΔG° < 0, ΔH° < 0, and ΔS° < 0) indicate that adsorption of BPA on AC-HP was spontaneous and exothermic in nature. The regeneration of AC-HP showed excellent results after 5 cycles (95-93%). This work does not only provide a potential way to use argan nut shell but also represents a sustainable approach to synthesize AC-HP, which might be an ideal material for various applications (energy storage, catalysis, and environmental remediation).

A novel Pd-based catalyst hosted over a nitrogen enriched fibrous porous-organic-polymer with a high density of step sites and exhibits versatile catalytic performance over different types of vegetable oils to furnish long chain diesel-range alkanes.