In this study, biodegradable starch film was developed from pineapple stem waste as a substitute for non-biodegradable petroleum-based films for single-use applications where strength is not too demanding. High amylose starch from a pineapple stem was used as the matrix. Glycerol and citric acid were used as additives to adjust the ductility of the material. Glycerol content was fixed at 25% while that of citric acid varied from 0 to 15% by weight of starch. Films with a wide range of mechanical properties can be prepared. As more citric acid is added, the film becomes softer and weaker, and has greater elongation at the break. Properties range from a strength of about 21.5 MPa and 2.9% elongation to a strength of about 6.8 MPa and 35.7% elongation. An X-ray diffraction study showed that the films were semi-crystalline. The films were also found to be water-resistant and can be heat-sealed. An example of a single-use package was demonstrated. A soil burial test confirmed that the material was biodegradable and completely disintegrated into sizes smaller than 1 mm within one month.
Pineapple materials sourced from agricultural waste have been employed to process novel bio-degradable rigid composite foams. The matrix for the foam consisted of starch extracted from pineapple stem, known for its high amylose content, while the filler comprised non-fibrous cellulosic materials sourced from pineapple leaf. In contrast to traditional methods that involve preparing a batter, this study adopted a unique approach where the starch gel containing glycerol were first formed using a household microwave oven, followed by blending the filler into the gel using a two-roll mill. The resulting mixture was then foamed at 160 °C using a compression molding machine. The foams displayed densities ranging from 0.43–0.51 g/cm3 and exhibited a highly amorphous structure. Notably, the foams demonstrated an equilibrium moisture content of approximately 8–10% and the ability to absorb 150–200% of their own weight without disintegration. Flexural strengths ranged from 1.5–4.5 MPa, varying with the filler and glycerol contents. Biodegradability tests using a soil burial method revealed complete disintegration of the foam into particles measuring 1 mm or smaller within 15 days. Moreover, to showcase practical applications, an environmentally friendly single-use foam tray was fabricated. This novel method, involving gel formation followed by filler blending, sets it apart from previous works. The findings highlight the potential of pineapple waste materials for producing sustainable bio-degradable foams with desirable properties and contribute to the field of sustainable materials.
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