We investigated the evolution in silver nanoparticle (AgNP) properties during a series of 10-50 day experiments on suspensions with different pH (5-9), electrolyte type (NaNO and NaCl) and concentration (2 and 6 mM), Suwannee River humic acid (SRHA) concentration (0-13.2 mg C/L), and light exposure (artificial sun light exposure for 8 h per day or dark). Of these factors, pH most influenced the AgNPs' properties as it modifies surface charge as well as AgNP dissolution and oxidation and Ag reduction reactions. As a result, particle behavior differed in basic and acidic conditions. Trends with pH varied, however, based on the electrolyte and SRHA concentration. In the presence of chloride which forms AgCl(s), for example, we observed the particle size decreased with increasing pH. The opposite was observed in identical systems in NaNO. This behavior was modified by SRHA, with increasing SRHA reducing dissolution and enhancing stability. Light exposure enhanced processes resulting in AgNP dissolution, resulting in higher dissolved Ag concentrations than under similar conditions in the dark. Overall, our results highlight how AgNP properties evolve over time and provide insight needed to confidently extend model system behavior to predict the environmental fate of AgNPs.

Thirteen states in the United States allow the spreading of O&G wastewaters on roads for deicing or dust suppression. In this study, the potential environmental and human health impacts of this practice are evaluated. Analyses of O&G wastewaters spread on roads in the northeastern, U.S. show that these wastewaters have salt, radioactivity, and organic contaminant concentrations often many times above drinking water standards. Bioassays also indicated that these wastewaters contain organic micropollutants that affected signaling pathways consistent with xenobiotic metabolism and caused toxicity to aquatic organisms like Daphnia magna. The potential toxicity of these wastewaters is a concern as lab experiments demonstrated that nearly all of the metals from these wastewaters leach from roads after rain events, likely reaching ground and surface water. Release of a known carcinogen (e.g., radium) from roads treated with O&G wastewaters has been largely ignored. In Pennsylvania from 2008 to 2014, spreading O&G wastewater on roads released over 4 times more radium to the environment (320 millicuries) than O&G wastewater treatment facilities and 200 times more radium than spill events. Currently, state-by-state regulations do not require radium analyses prior to treating roads with O&G wastewaters. Methods for reducing the potential impacts of spreading O&G wastewaters on roads are discussed.

Particulate matter (PM) generated from dirt and gravel roads is a concern for both human and environmental health. To help reduce the amount of PM generated, many states allow the use of water coproduced from oil and gas wells (i.e., brines) as road dust suppressants. However, few methods exist to quantify the effectiveness of these brines and other dust suppressants. Here we designed and tested a bench-scale method to test the efficacy of dust suppressants on dirt and gravel road materials. The Standard Proctor test was modified to create discs of road aggregate that could be treated with dust suppressant, dried, and then tumbled in a mechanical drum attached to an aerosol monitor that measured PM generated within the drum. Using two types of road aggregate (DSA and 2RC) and a combination of nine simulated brines, the effects of brine total dissolved solids (TDS), and sodium adsorption ratio (SAR) on dust suppression were calculated. The effects of moisture content and aggregate type were also observed. Higher TDS and lower SAR were found to be good predictors of dust-suppression effectiveness, with the degree of effectiveness partially dependent on the type of road aggregate. The test method provides a means to quickly and reproducibly compare effectiveness of dust suppressants, with other variables such as aggregate type and moisture content, to accurately estimate dust suppression. Comparisons of dust measurements collected within the laboratory and vehicle-based measurements offer the ability to relate laboratory results to conditions encountered on dirt and gravel roads.

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