Autoionizing resonances that arise from the interaction of a bound single-excitation with the continuum can be accurately captured with the presently used approximations in time-dependent density functional theory (TDDFT), but those arising from a bound double excitation cannot. In the former case, we explain how an adiabatic kernel, which has no frequency-dependence, can yet generate the strongly frequency-dependent resonant structures in the interacting response function, not present in the Kohn-Sham response function. In the case of the bound double-excitation, we explain that a strongly frequency-dependent kernel is needed, and derive one as an a posteriori correction to the usual adiabatic approximations in TDDFT. Our approximation becomes exact for an isolated resonance in the limit of weak interaction, where one discrete state interacts with one continuum. We derive a "Fano TDDFT kernel" that reproduces the Fano lineshape within the TDDFT formalism, and also a dressed kernel, that operates on top of an adiabatic approximation. We illustrate our results on a simple model system.

Abstract. We consider the Schrödinger equation with a Hamiltonian given by a second order difference operator with nonconstant growing coefficients, on the half one dimensional lattice. This operator appeared first naturally in the construction and dynamics of noncommutative solitons in the context of noncommutative field theory. We prove pointwise in time decay estimates with the decay rate t −1 log −2 t, which is optimal with the chosen weights and appears to be so generally. We use a novel technique involving generating functions of orthogonal polynomials to achieve this estimate.

Abstract. We consider the Schrödinger equation with a Hamiltonian given by a second order difference operator with nonconstant growing coefficients, on the half one dimensional lattice. This operator appeared first naturally in the construction and dynamics of noncommutative solitons in the context of noncommutative field theory. We construct a ground state soliton for this equation and analyze its properties. In particular we arrive at ∞ and 1 estimates as well as a quasi-exponential spatial decay rate.Mathematics subject classification. 35Q40, 35Q55, 39A05.

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