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a b s t r a c tUltrasonic welding offers ability to weld thin layers of malleable metals at low temperature and low power consumption. During ultrasonic welding, intensive material interactions occur due to the severe plastic deformation (SPD) and frictional heat generation, which leads to the microstructural change. Different grain microstructures have been observed after different ultrasonic welding conditions. Theory of the microstructural evolution was for the first time hypothesized as three regimes, namely SPD, dynamic recrystallization (DRX) and grain growth according to the material thermomechanical loading conditions. A novel metallo-thermo-mechanically coupled model was developed to model the temperature-dependent mechanical deformation and microstructural evolution during the ultrasonic spot welding process. The numerical analysis was carried out with a three-dimensional (3D) finite element model using DEFORM 11.0. The material constitutive model considered cyclic plasticity, thermal softening and acoustic softening. Dynamic recrystallization and grain growth kinetics laws were applied to simulate the microstructural evolution under different welding time durations. The simulation results demonstrated that the essential characteristics of the deformation field and microstructure evolution during ultrasonic welding were well captured by the metallo-thermo-mechanically coupled model. The numerical framework developed in this study has been shown to be a powerful tool to optimize the ultrasonic welding process for its mechanical properties and microstructures.

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Extreme wetting activities of laser-textured metal alloys have received significant interest due to their superior performance in a wide range of commercial applications and fundamental research studies. Fundamentally, extreme wettability of structured metal alloys depends on both the surface structure and surface chemistry. However, compared with the generation of physical topology on the surface, the role of surface chemistry is less explored for the laser texturing processes of metal alloys to tune the wettability. This work introduces a systematic design approach to modify the surface chemistry of laser textured metal alloys to achieve various extreme wettabilities, including superhydrophobicity/superoleophobicity, superhydrophilicity/superoleophilicity, and coexistence of superoleophobicity and superhydrophilicity. Microscale trenches are first created on the aluminum alloy 6061 surfaces by nanosecond pulse laser surface texturing. Subsequently, the textured surface is immersion-treated in several chemical solutions to attach target functional groups on the surface to achieve the final extreme wettability. Anchoring fluorinated groups (−CF2– and −CF3) with very low dispersive and nondispersive surface energy leads to superoleophobicity and superhydrophobicity, resulting in repelling both water and diiodomethane. Attachment of the polar nitrile (CN) group with very high nondispersive and high dispersive surface energy achieves superhydrophilicity and superoleophilicity by drawing water and diiodomethane molecules in the laser-textured capillaries. At last, anchoring fluorinated groups (−CF2– and −CF3) and polar sodium carboxylate (−COONa) together leads to very low dispersive and very high nondispersive surface energy components. It results in the coexistence of superoleophobicity and superhydrophilicity, where the treated surface attracts water but repels diiodomethane.

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