The complex zeros of partition functions were originally investigated by Lee and Yang to explain the behavior of condensing gases. Since then, Lee-Yang zeros have become a powerful tool to describe phase transitions in interacting systems. Today, Lee-Yang zeros are no longer just a theoretical concept; they have been determined in recent experiments. In one approach, the Lee-Yang zeros are extracted from the high cumulants of thermodynamic observables at finite size. Here, we employ this method to investigate a phase transition in a molecular zipper. From the energy fluctuations in small zippers, we can predict the temperature at which a phase transition occurs in the thermodynamic limit. Even when the system does not undergo a sharp transition, the Lee-Yang zeros carry important information about the large-deviation statistics and its symmetry properties. Our work suggests an interesting duality between fluctuations in small systems and their phase behavior in the thermodynamic limit. These predictions may be tested in future experiments.

Lee-Yang zeros are complex values of an external control parameter at which the partition function vanishes for a many-body system of finite size. In the thermodynamic limit, the Lee-Yang zeros approach the critical value on the real-axis where a phase transition occurs. Partition function zeros have for many years been considered a purely theoretical concept, however, the situation is changing now as Lee-Yang zeros have been determined in several recent experiments. Motivated by these developments, we here devise a direct pathway from measurements of partition function zeros to the determination of critical points and universal critical exponents of continuous phase transitions. To illustrate the feasibility of our approach, we extract the critical exponents of the Ising model in two and three dimensions from the fluctuations of the total energy and the magnetization in surprisingly small lattices. Importantly, the critical exponents can be determined even if the system is away from the phase transition, for example at a high temperature. As such, our method provides an intriguing perspective for investigations of phase transitions that may be hard to reach experimentally, for instance at very low temperatures or at very high pressures.

Phase transitions are typically accompanied by nonanalytic behaviors of the free energy, which can be explained by considering the zeros of the partition function in the complex plane of the control parameter and their approach to the critical value on the real axis as the system size is increased. Recent experiments have shown that partition function zeros are not just a theoretical concept. They can also be determined experimentally by measuring fluctuations of thermodynamic observables in systems of finite size. Motivated by this progress, we investigate here the partition function zeros for the Curie-Weiss model of spontaneous magnetization using our recently established cumulant method. Specifically, we extract the leading Fisher and Lee-Yang zeros of the Curie-Weiss model from the fluctuations of the energy and the magnetization in systems of finite size. We develop a finite-size scaling analysis of the partition function zeros, which is valid for mean-field models and which allows us to extract both the critical values of the control parameters and the critical exponents, even for small systems that are away from criticality. We also show that the Lee-Yang zeros carry important information about the rare magnetic fluctuations as they allow us to predict many essential features of the large-deviation statistics of the magnetization. This finding may constitute a profound connection between Lee-Yang theory and large-deviation statistics.

We investigate the Ising model in one, two, and three dimensions using a cumulant method that allows us to determine the Lee-Yang zeros from the magnetization fluctuations in small lattices. By doing so with increasing system size, we are able to determine the convergence point of the Lee-Yang zeros in the thermodynamic limit and thereby predict the occurrence of a phase transition. The cumulant method is attractive from an experimental point of view since it uses fluctuations of measurable quantities, such as the magnetization in a spin lattice, and it can be applied to a variety of equilibrium and nonequilibrium problems. We show that the Lee-Yang zeros encode important information about the rare fluctuations of the magnetization. Specifically, by using a simple ansatz for the free energy, we express the large-deviation function of the magnetization in terms of Lee-Yang zeros. This result may hold for many systems that exhibit a first-order phase transition.

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