Metal complexes of Schiff base ligand (5-bromo-3-methoxysalicyliden-p-iminoacetophenone oxime) derived from 5-bromo-3-methoxsalicylaldehyde and p-aminoacetophenoneoxime is reported. Schiff base was found to be bidentate ligand involving the imino nitrogen and carboxyl oxygen atoms in the complexes. Metal to ligand ratio were found to be 1:2 for all of the complexes. Co(II), Ni(II), and Zn(II) complexes have been found tetrahedral geometry and Cu(II) complex has been found four coordinated geometry. The complexes are found to have the formulae [M(L)2]. The compounds obtained have been characterized by their elemental analyses, IR, 1H-NMR, 13C-NMR, UV spectra, magnetic susceptibility and thermogravimetric analyses (TGA).