This study examined the biodégradation of phenol by Ralstonia eutropha in a Kissiris-immobiiized ceii bioreactor (ICB), operated in a repeated batch recycling mode.. The steady biodégradation rate of 23.7 mg/g/h, over a wide range of the initial phenol concentrations up to 1400 mg/L in the ICB, indicated an increased tolerance limit of the Kissiris-immobilized cells towards phenol. Both Haldane and Luong substrate inhibition models were used to describe biodégradation kinetic of free cells system. The Haldane equation gave the following values for the biokinetic parameters: |.in,ax= 0.36 h~', Ks= 4{).48 mg/L, and K¡= 181.9 mg/L. However, according to the Luong model, these parameters were Hrnax= 0.23 h ', I

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Olive oil mill wastewater (OMW) has a high polluting power, with total phenolics (TP) around 2.5 g l(-1) and chemical oxygen demand (COD) 85 g l(-1). Biological systems offer advantages in treating this type of agro-industrial wastewater. The performance of phenol-adapted Ralstonia eutropha for aerobic biotreatment of OMW has been studied, and a TP concentration of 250 mg l(-1) found to be fully degraded within 24 h. This simple procedure may be adopted as a pretreatment prior to the normal aerobic or anaerobic techniques used for treating OMW. The biodegradative capability of this non-pathogenic gram-negative bacterium towards the TP and COD content of OMW has been evaluated. The adapted free cells were found able to decrease TP and COD in the undiluted OMW by 56% and 42%, respectively. The Monod equation was found suitable to describe the capacity of the cells for growing on undiluted OMW, giving micromax 0.083 per day and Ks = 1846 mg l(-1). Using a packed-bed reactor the performance of loofa-immobilized R. eutropha was assessed and the reduction in TP and COD shown to be 73% and 64%, respectively.

In the present research, water soluble thioglycolic acid-capped CdS quantum dots (QDs) were synthesized by chemical precipitation method. The characteristics of prepared quantum dots were determined using X-Ray Diffraction (XRD) and Transmission Electron Microscopy (TEM). The obtained results revealed that CdS QDs have 5.60 nm crystallite size, hexagonal wurtzite structure and spherical morphology with less than 10 nm diameter. The photoluminescence (PL) spectroscopy was performed in order to study the effect of the presence of starch solutions. Blue emission peaks were positioned at 488 nm and its intensity quenched by increasing the concentration of starch solutions. The result of PL quenches in range of studied concentrations (0-100 ppm) was best described by Michaelis-Menten model. The amount of Michaelis constant (Km) for immobilized α-amylase in this system was about 68.08 ppm which showed a great tendency of enzyme to hydrolyze the starch as substrate. Finally, the limit of detection (LOD) was found to be about 2.24 ppm.