Aggregate formation of a didodecyldimethylammonium bromide (DDAB) and didodecyldimethylammonium chloride (DDAC) mixture in aqueous solution was investigated. The concentration vs composition diagram of aggregate formation was constructed by analyzing the surface tension, turbidity, and electrical conductivity data. The cryogenic transmission electron microscopy was applied to several representative points in the diagram and provided information of the morphology of aggregates. The sequence of monomer (m) - m + small aggregate (A) - m + A + vesicle (V) - m + V was concluded with increasing total concentration of surfactants at all mixing ratios. The compositions of counterions in A and V were estimated on the basis of thermodynamic consideration and examined from the viewpoint of asymmetry of constituents and uneven distribution between outer and inner monolayers of a vesicle bilayer. Vesicle surfaces were suggested to abound in chloride ions compared to bulk solution, which is opposite to spherical micelle surfaces.

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SUMMARY Seismic signals during explosive eruptions have been correlated to eruption size or eruption volume flux for individual eruptive episodes. However, the universality of these correlations has yet to be confirmed. We quantified the sources of high-frequency seismic signals associated with sub-Plinian and Vulcanian eruptions at Kirishima (Japan), Tungurahua (Ecuador) and other volcanoes in Japan using a simple approach based on highly scattered seismic waveform characteristics. We found that eruption plume heights scale to seismic source amplitudes and are described by two relations depending on the value of source amplitudes: power-law and exponential relations for plume height >6 km and <6 km, respectively. Though conceptually similar, our scaling relations differ from the previously proposed relation based on reduced displacement. By comparing seismic and geodetic data during sub-Plinian eruptions at Kirishima, we found that the source amplitude is proportional to eruption volume flux. Combining these relations, we show that our scaling relation for Plinian eruptions is consistent with predictions from plume dynamics models. We present a source model to explain the proportionality between the source amplitude and eruption volume flux assuming a vertical crack or a cylindrical conduit as the source. The source amplitude can be estimated in seconds without any complicated data processing, whereas eruption plumes take minutes to reach their maximum heights. Our results suggest that high-frequency seismic source amplitudes are useful for estimating plume heights in real time.

Summary Seismic source amplitudes determined by using the amplitudes of high-frequency (5−10 Hz) tremor signals generated by sustained explosive eruptions have been shown to be related to eruption plume height by power-law and exponential relations and to eruption volume flux by a proportional relation. We further examined these relations and extended this source quantification approach to investigate eruption duration by using the envelope width, defined by the ratio of the cumulative source amplitude to the source amplitude. We first confirmed that the relationship between source amplitude and plume height proposed by a previous study holds for small eruptions at Nevado del Ruiz (Colombia), although slight modifications were required. We then showed that the relations of envelope width with source amplitude and with cumulative source amplitude of eruption tremor associated with sub-Plinian eruptions at Kirishima (Japan) and Tungurahua (Ecuador) could be described by a power law. The source amplitude functions of these tremors were characterized by three periods and could be approximated by a trapezoidal shape. A power-law function fitted to the relation between eruption volume and eruption duration obtained from these relations was similar to that estimated by fitting a power-law function to previously reported eruption volume and duration data of well-documented silicic and andesitic eruptions. Our results suggest that eruption duration may systematically vary with eruption volume when the conduit is stably open during the second period of the trapezoidal source amplitude function. This study demonstrated that source amplitudes can be used for real-time predictions of both plume height and eruption duration, which in turn may be used to estimate ashfall distributions and tephra transport for local residents and aviation operations.