No abstract

The main goal of this paper is to acquire more insight into the relationship between wall and piston impingement of liquid fuel and unburnt hydrocarbon emissions (UHC) emissions, under early direct injection (EDI) premixed charge compression ignition (PCCI) operating conditions. To this end, the vaporization process is modeled for various operating conditions using a commercial CFD code (StarCD). Predicted values for liquid core penetration, or liquid length LL , have been successfully checked against experimental data from literature over a wide range of operating conditions. Next, the correlation between the CFD results for wall and piston impingement and measured UHC emissions is studied. The diesel fuel used in the experiments is modeled as n-dodecane and n-heptadecane, representing the low and high end of the diesel boiling range, respectively. A distinction is made between liquid spray impingement on the piston surface and cylinder liner. For a conventional DI diesel nozzle, the high UHC emissions in the EDI PCCI regime correlate well with modeled cylinder wall impingement. Conversely, piston impingement is negligible in this regime. Accordingly, it may be assumed that the primary cause for high UHC emissions in the EDI PCCI regime, using conventional DI nozzles, is caused by liquid spray impingement against the cylinder liner. In this regime it was found that a higher intake and fuel temperature, as well as an elevated intake pressure have a positive effect on both UHC emissions and the spray impingement against the cylinder wall. This provides additional evidence that the two parameters (i.e. UHC and wall impingement) are linked. Lastly, the impact of nozzle cone angle is investigated. When adopting a narrow cone angle nozzle in the EDI PCCI regime, wall impingement is negligible and piston wetting becomes the dominant source of UHC emissions.

No abstract

The ultra rich combustion (partial oxidation) of natural gas to hydrogen and carbon monoxide is theoretically and experimentally investigated. The effect of the process parameters equivalence ratio, residence time, pressure, and composition of the oxidizer is explored. Computations are performed with the use of the chemical kinetics simulation package CHEMKIN. First, the ultra rich combustion process is modeled as a freely propagating flame in order to establish the rich flame propagation properties. An Arrhenius correlation of the laminar flame speed with the adiabatic flame temperature is found with activation temperature 20,000 K. Subsequently, perfectly stirred reactor (PSR) computations were performed. From these, it is concluded that optimal natural gas conversion to hydrogen and carbon monoxide requires a residence time of at least 50 ms and, depending on residence time, an equivalence ratio between 2 and 4. To reach chemical equilibrium in ultra rich mixtures, the residence time is very long (>1000 ms). The model predictions are validated by experiments on ultra rich combustion of natural gas by means of air enriched to 40% oxygen concentration at up to 3 bar and 300 kW. The effect of equivalence ratio at residence time 50 ms was investigated. Good comparison was found between measurements and model predictions on carbon monoxide, hydrogen, and the soot precursor acetylene. It can be concluded that the model provides reliable information on product gas concentrations as a result of ultra rich combustion of natural gas.

No abstract