In the present research presents influence of coupling agent 1 % triethoxymethyl silane sprayed on to the wollastonite particulate powder before it dispersed into the vinylester/composites. Firstly two different composites were developed in which wollastonite is filled with vinylester resin and same wollastonite was sprayed with coupling agent 1 % triethoxymethyl silane then filled with vinylester resin. The particle functionalization with a bi-functional coupling agent 1 % triethoxymethyl silane was observed to have a significant effect on the curing process and subsequent physical properties of the composites. Wollastonite functionalization favors the composite fabrication with a lower curing temperature as compared to the as-received particle filled vinyl ester resin composites. Thermogravimetric analysis showed an increased thermo-stability in the particles functionalized filled vinyl ester resin composites as compared to the unmodified particle filled counterparts. The uniform particle dispersion and the chemical bonding between filler and vinyl ester resin matrix were found to contribute to the increased thermal stability and enhanced tensile strength and modulus.

In the present paper evaluates laminated aramidic bi-woven fibers reinforced in polyestervinylester blended composites. The Duo polymers, polyester-vinylester were blended using in situ polymerization technique. Four planar layers were made simultaneously and keeping one over another and each layer make sure to be weighed off 15% were maintained in all layers with different orientations. Pre-assumed Layer-1(50/50) 50 %, 0º; Layer-2(35/35/30) 35 % 0º, 35 % +45º, 30 %,0; Layer-3 (25/50/25) 25 % 0º, 50% +45º, 25-45º; Layer-4 (25/25/25/25) (2 5% 0º, 25 % +45º, 25 % -45º, 25 % 90º). Tthe composite was prepared with the help of hand layup technique. Test ready specimens were the help of shearing machine in accordance with ASTM. It was observed that, polyester and vinylester had good miscibility makes combined solid material. Flexural strength, tensile strength was improved up to 3ed layer, decreases after, whereas flexural modulus and tensile modulus were linearly increased up to 4 th layer. Thermal stability and glass transition temperature were also found satisfactory for all the laminated layers. Chemical resistance was good for the entire chemical except toluene.