Plasma polymerized allylamine (ppAA) films were deposited in a radio‐frequency glow discharge plasma reactor using a continuous‐wave mode and varying the discharge power from 15 to 125 W. The deposition rate reached 26 nm · min−1 and was constant within at least half an hour of process. The chemical structure and elemental composition of the deposited films were investigated by Fourier transform infrared and X‐ray photoelectron spectroscopies, whereas surface properties were analyzed by atomic force microscopy and surface free energy measurement. A special focus is given to the stability of ppAA in aqueous media and primary amine quantification. The use of fluorescent microscopy and UV‐Visible spectroscopy enabled us to detect and quantify the primary amine, respectively. All the studied parameters varied widely with enhanced power with a transition point around 50 W. Over this value, the results remain relatively unchanged.
Near-field microwave radiometry and radiometric imaging are non-invasive techniques that are able to provide temperature information at a depth of up to several centimetres in subcutaneous tissues. They are based on the measurement of microwave electromagnetic thermal noise. This paper describes the basic principles, measurement methods and limitations of the techniques and the results of clinical studies, and it reviews recent progress.
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