Our work shows that the irradiation procedure leads to an increase in the number and size of nanovesicles along with the dose. The functionality of RBC can be affected from changes in the roughness, becoming more fragile and susceptible to breakage.

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This work describes the preparation of thermosensitive chitosan‐graft‐poly(N‐vinylcaprolactam) nanoparticles by ionic gelation and their potential use as a controlled drug delivery system, using doxorubicin as a model drug. A systematic study of the effect of the main processing parameters on both the size and thermoresponsive behavior of nanoparticles was investigated. The size of the particles is strongly dependent on the length of the poly(N‐vinylcaprolactam) grafted chains and the concentration of the copolymer and crosslinking agent solutions. The molecular structure of the copolymer plays an essential role in the phase transition temperature of the particles, which decreases with the length of PVCL grafted chain. The system displayed proper drug‐association parameters, and the drug‐loaded nanoparticles exhibited dose‐dependent cytotoxicity. A significant increase in the doxorubicin delivery rate was observed above the phase transition temperature (40 °C). These features indicate that these nanoparticles are suitable for the development of a new thermally controlled anti‐cancer drug delivery system. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47831.

Europium-doped KCl1−xBrx mixed crystals have been studied as a selective ultraviolet (UV) detector material in the actinometric region (200–300 nm). Thermoluminescence glow curves of room-temperature UV-irradiated samples were analyzed as a function of composition x and irradiation wavelength. A thermoluminescence enhancement, relative to the pure KCl and KBr end components is found; for 210–300 nm irradiation the KCl40Br60:Eu2+ solid solution presents a significant increase in thermoluminescence efficiency.

Chemical vapor deposition (CVD) diamond has not found extensive application as a thermoluminescence (TL) dosimeter, mainly because its TL glow curve shape is not reproducible. A slight variation in the growing conditions may result in strong changes in the morphology, microstructure, and surfaceimpurity-related defects, considerably affecting the TL glow curve features. In order to study the main TL characteristics under controlled growing conditions, we present results on three 0.5, 1.0, and 4.0 m thick hot filament CVD (HFCVD) diamond films grown on Si (100) substrates. The recorded TL glow curves were resolved into individual peaks by a home-made deconvolution program and the kinetic parameters of the peaks were extracted. The best fits of the TL glow curves were obtained using four peaks, except for the 4.0 m thick sample that required five TL components. All samples showed three high intensity TL peaks between 180-400 • C and a less intense one or two peaks in the 100-180 • C low-temperature region. The lowtemperature components all obey second-order kinetics while the high-temperature ones obey first and 1.6 order kinetics. The samples showed similar TL peaks with comparable kinetics parameters. It is concluded that the manufacturing of high quality HFCVD diamond may require a further improvement in the growing process in order to exploit its excellent tissueequivalence properties in clinical and medical applications.