During the last half century, the tremendous development of computers based on von Neumann architecture has led to the revolution of the information technology. However, von Neumann computers are outperformed by the mammal brain in numerous data‐processing applications such as pattern recognition and data mining. Neuromorphic engineering aims to mimic brain‐like behavior through the implementation of artificial neural networks based on the combination of a large number of artificial neurons massively interconnected by an even larger number of artificial synapses. In order to effectively implement artificial neural networks directly in hardware, it is mandatory to develop artificial neurons and synapses. A promising advance has been made in recent years with the introduction of the components called memristors that might implement synaptic functions. In contrast, the advances in artificial neurons have consisted in the implementation of silicon‐based circuits. However, so far, a single‐component artificial neuron that will bring an improvement comparable to what memristors have brought to synapses is still missing. Here, a simple two‐terminal device is introduced, which can implement the basic functions leaky integrate and fire of spiking neurons. Remarkably, it has been found that it is realized by the behavior of strongly correlated narrow‐gap Mott insulators subject to electric pulsing.
[ # ] these authors contributes equally to this work Keywords: resistive switching, non-volatile memory, Mott insulator, metal-insulator transitionThe fundamental building blocks of modern silicon-based microelectronics, such as double gate transistors in non-volatile Flash memories, are based on the control of electrical resistance by electrostatic charging. Flash memories could soon reach their miniaturization limits mostly because reliably keeping enough electrons in an always smaller cell size will become increasingly difficult [1] . The control of electrical resistance at the nanometer scale therefore requires new concepts, and the ultimate resistance-change device is believed to exploit a purely electronic phase change such as the Mott insulator to insulator transition [ 2 ].Here we show that application of short electric pulses allows to switch back and forth between an initial high-resistance insulating state ("0" state) and a low-resistance "metallic" state ("1" state) in the whole class of Mott Insulator compounds AM 4 X 8 (A = Ga, Ge; M= V, Nb, Ta; X = S, Se). We found that electric fields as low as 2 kV/cm induce an electronic phase change in these compounds from a Mott insulating state to a metallic-like state. Our results suggest that this transition belongs to a new class of resistive switching and might be explained by recent theoretical works predicting that an insulator to metal transition can be achieved by a simple electric field in a Mott Insulator [3,4,5] . This new type of resistive switching has potential to build up a new class of Resistive Random Access Memory (RRAM) with fast writing/erasing times (50 ns to 10 µs) and resistance ratios R/R of the order of 25% at room temperature.
Mott transitions induced by strong electric fields are receiving growing interest. Recent theoretical proposals have focused on the Zener dielectric breakdown in Mott insulators. However, experimental studies are still too scarce to conclude about the mechanism. Here we report a study of the dielectric breakdown in the narrow-gap Mott insulators GaTa 4 Se 8 À x Te x . We find that the I-V characteristics and the magnitude of the threshold electric field (E th ) do not correspond to a Zener breakdown, but rather to an avalanche breakdown. E th increases as a power law of the Mott-Hubbard gap (E g ), in surprising agreement with the universal law E th pE g 2.5 reported for avalanche breakdown in semiconductors. However, the delay time for the avalanche that we observe in Mott insulators is over three orders of magnitude greater than in conventional semiconductors. Our results suggest that the electric field induces local insulator-to-metal Mott transitions that create conductive domains that grow to form filamentary paths across the sample.
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