This paper presents the results of experiments carried out to reveal the influence of the initial parameters of the thermite mixture Al–CuO on the signs of a chemical reaction between its components. Initial parameters were the characteristics of the starting components, preparation conditions and characteristics of the mixture and samples, experimental schemes, methods of initiation. The most important parameter was the preliminary mechanical activation of mixture. The prepared mixture with controlled porosity was placed in experimental assemblies and a chemical reaction was initiated. Values and tendencies of the brightness temperature and the propagation rate of reaction area were determined for different initial parameters of mixture and initiation conditions. The reaction in the volume of the experimental assembly goes into flare combustion in open space. Values of brightness temperature at the stage of flare formation have a stochastic character, determined by the random distribution of reaction sites in the initial volume of the components. A high-speed camera, a pyrometer, photoelectronic and electrocontact sensors were used as diagnostic tools. The final goal of the study is to optimize parameters of mechanical activation of mixture for its effective applying in various conditions.

The results of experiments to determine the role of structural schemes for the ignition of a mechanically activated thermite mixture Al–CuO and the formation of its combustion flame are presented. The reaction initiated in the bulk of the experimental assembly transforms into torch combustion in an open space. The dynamics of the volume of the flame reaction region was determined. The stage of flame formation has a stochastic character, determined by the random distribution of the reaction centres in the initial volume of the components. A high-speed camera, a pyrometer and electro contact sensors were used as diagnostic tools. The ultimate goal of the study was to optimize the conditions for the flame formation of this mixture for its effective use with a single ignition of various gas emissions.

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The combustion wave propagation in Al–CuO and Al–Bi2O3 termite mixtures was experimentally investigated. Waveforms of electric current through the reaction area between electrodes with a given potential difference, chronograms of piezo- and photodiode response, the data of pyrometric measurements, as well as photos of the glowing area were obtained and analyzed. There were revealed the advance filtration of the gas component through pores of mixture, the generation of charges providing considerable electrical conductivity of chemical reaction products, the connection of electrical conductivity dynamics with the optical radiation of the chemical conversion region.