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The Structure of Fullerene Compounds -[30 refs.]. -(AVENT, A. G.; BENITO, A. M.; BIRKETT, P. R.; DARWISH, A. D.; HITCHCOCK, P. B.; KROTO, H. W.; LOCKE, I. W.; MEIDINE, M. F.; O'DONOVAN, B. F.; PRASSIDES, K.; J. Mol. Struct. 436-437 (1997) 1-9; Sch. Chem. Mol. Sci., Univ. Sussex, Brighton BN1 9QJ, UK; EN)

1997 other polycyclic compounds other polycyclic compounds Q 1150 -111Phosphine-Catalyzed Cycloaddition of Buta-2,3-dienoates and But-2ynoates to (60)Fullerene.-Three phosphine catalysts are tested in the reaction of (60)fullerene ( I) with esters (II) and (IV). PBu3 is found to be the most reactive under the optimized reaction conditions. The structure of product (III) is characterized by spectroscopic methods and X-ray analysis. -(O'DONOVAN, B. F.; HITCHCOCK, P. B.; MEIDINE, M. F.; KROTO, H. W.; TAYLOR, R.; WALTON, D. R. M.; Chem. Commun. (Cambridge) (1997) 1, 81-82; Sch. Chem., Phys. Environ. Sci., Univ. Sussex, Brighton, East Sussex BN1 9QJ, UK; EN)