no analysis 5.13 C. Tri-n-octylamine Amine dry (No H2S04) <1 0.277 Sulfate wet 0.494 2.5 6.77 Bisulfate wet .943 0.94 5.40deviations from linearity in the measurement of dielectric constants of various triand tetraalkylammonium pier ates and bromides in benzene. They attributed this effect to an increase in aggregation with concentration, and noted that very symmetrical molecules showed little deviation from linearity, while very unsymmetrical ones showed large deviations. For the present solutes, the light scattering measurements indicated monodisperse aggregates; in addition, there is apparently little or no correlation between the non-linearity observed here and molecular symmetry. It seems likely that some other effect is responsible for the deviations observed.
The kinetics of the deposition and dissolution of indium (from indium amalgam) in indium sulfate solutions at pH 2.5 have been studied by observing variations of overpotential during individual constant current pulses. The electrode was in the form of a hanging drop of the amalgam, which was renewed for each pulse. The steady-state activation overpotential was reached approximately 1 msec after application of the pulse, which corresponds to a mean value of double layer capacity of 25.4 ~F/cm ~. Plots of the activation overpotential vs. log current density show good Tafel relations in both the cathodic and anodic regions. Analysis of these data shows the mechanism to consist of three consecutive electron transfer steps ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 138.38.0.53 Downloaded on 2015-06-13 to IP
In a previous paper the kinetics of the deposition and dissolution of indium was studied by a galvanostatic method of single current pulses. At c.d. higher than 2.5 x 10 -3 amp/cm 2 a change in the mechanism of the deposition and dissolution of indium was observed. To study the phenomenon, the cathodic and ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 138.251.14.35 Downloaded on 2015-03-20 to IP ) unless CC License in place (see abstract). ecsdl.org/site/terms_use address. Redistribution subject to ECS terms of use (see 138.251.14.35 Downloaded on 2015-03-20 to IP
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