Precipitation of ammonium together with phosphate and magnesium is a possible alternative for lowering the nitrogen content of wastewater. In this study we examine the removal of ammonium nitrogen and phosphorus from slurry-type swine wastewater containing high concentrations of nutrients by the addition of phosphoric acid along with either calcium oxide or magnesium oxide, which leads to the crystallization of insoluble salts such as hydroxyapatite and struvite. The struvite crystallization method showed a high capacity for the removal of nitrogen when magnesium oxide and phosphoric acid were used as the magnesium and phosphate sources, respectively. When it was applied to swine wastewater containing a high concentration of nitrogen, the injection molar ratio of Mg2+:NH4+:PO4(3-) that gave maximum ammonium nitrogen removal was 3.0:1.0:1.5.

This research aimed to effectively remove high-concentration organic matter and nutrients from slurry-type swine waste using a combined upflow anaerobic sludge blanket reactor with the dissolved air flotation/aerobic submerged biofilm/anoxic/aerobic process. The upflow anaerobic sludge blanket reactor was operated at an organics volumetric loading rate of 3.2-6.1 kg COD/m3/day, and the removal rates of COD were 53.9-65.5%. The removal rate of COD of the overall process was more than 99%. In the aerobic submerged biofilm, over 95% of ammonium nitrogen was removed at a volumetric loading rate of 0.08-0.16 kg NH4+-N/m3/day. The specific denitrification rate was 0.257 g NO3-N/g MLVSS/day and the removal rate of total nitrogen was 86.7%. Phosphorus was removed by flocculation in the dissolved air flotation process, and 0.16 g of PO4-P was removed by 1 g of ferric ion.