In this paper, fire resistance of natural fabrics and their composites were
experimentally investigated. Special interest was given to use bio based
materials such as lignin, chlorophosphates, levulinic acid and cardanol in
order to exploit their capability to be utilized as flame retardants.
Dopamine hydrochloride was polymerized to polydopamine (PDA) and coated to
jute fabric surface. Scanning Electron Microscope (SEM) and
Thermogravimetric Analysis (TGA)/Derivative Thermogravimetric (DTG) analyses
were performed to examine surface morphology and effect of PDA to
degradation behaviour of jute fabrics. Real fire behaviour of non-coated and
coated fabrics was observed with torch burn test. UL-94 horizontal flame
propagation test was also utilized for composite samples. Limiting Oxygen
Index (LOI) testing that measures the minimum amount of oxygen required for
combustion, was carried out for assessing the ability of the composite
samples for their ability against flammability. PDA was seamlessly coated on
the surface of the jute fabrics with its surface-active feature without
damaging the structure of the fabric as observed in the SEM images. With the
support of this coating on the fabric surface, the increase of the
decomposition temperature of the material can be clearly seen in TGA/DTG
analyses and torch burn test showed the increase in the ignition time. UL-94
horizontal testing resulted in decrease in flame propagation rate of PDA
coated composite samples. In addition to this, when the mass loss rates
after combustion are examined, it is seen that there is a decrease in mass
loss in the coated fabrics. Jute fabrics, a type of natural fabric, can be
efficiently coated with PDA, and the fire retardant property of the PDA
coating on natural fabrics has been clearly demonstrated.
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